摘要
The rotationally resolved emission from HCl and HF up to ν = 4 was observed after photolysis of CF2CHCl at 193 nm using time-resolved Fourier-transform spectroscopy. The internal energy distribution showed that HCl is produced via the three-center, but HF via the four-center elimination. It was found that HF has an average rotational energy of 20±4 kJ mol-1 and a vibrational energy of 48±6 kJ mol-1 while HCl has an average rotational energy of 23±4 kJ mol-1 and a vibrational energy of 25±5 kJ mol-1.
原文 | English |
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頁(從 - 到) | 9785-9792 |
頁數 | 8 |
期刊 | Journal of Chemical Physics |
卷 | 117 |
發行號 | 21 |
DOIs | |
出版狀態 | Published - 1 12月 2002 |