Theoretical studies of ZEKE spectroscopy and dynamics of high Rydberg states

Yi Hsieh Wang; Yoshiaki Teranishi; H. Mineo; S. D. Chao; H. L. Selzle; H. J. Neusser; E. W. Schlag; S. H. Lin

doi:10.1016/j.cplett.2009.12.092

Theoretical studies of ZEKE spectroscopy and dynamics of high Rydberg states

Yi Hsieh Wang, Yoshiaki Teranishi, H. Mineo, S. D. Chao^*, H. L. Selzle, H. J. Neusser, E. W. Schlag, S. H. Lin

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物理研究所

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2 引文斯高帕斯（Scopus）

摘要

A main purpose of this Letter is to show how to employ the inverse Born-Oppenheimer approximation as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calculations of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diatomic molecule as an example.

原文	English
頁（從 - 到）	104-109
頁數	6
期刊	Chemical Physics Letters
卷	486
發行號	4-6
DOIs	https://doi.org/10.1016/j.cplett.2009.12.092
出版狀態	Published - 12 2月 2010

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10.1016/j.cplett.2009.12.092

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AU - Wang, Yi Hsieh

AU - Teranishi, Yoshiaki

AU - Mineo, H.

AU - Chao, S. D.

AU - Selzle, H. L.

AU - Neusser, H. J.

AU - Schlag, E. W.

AU - Lin, S. H.

PY - 2010/2/12

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AB - A main purpose of this Letter is to show how to employ the inverse Born-Oppenheimer approximation as a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE states. The calculations of channel couplings, quantum defects, intensity borrowing, vibrational and rotational autotionizations will be demonstrated by using a homonuclear diatomic molecule as an example.

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EP - 109

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 4-6

ER -

Theoretical studies of ZEKE spectroscopy and dynamics of high Rydberg states

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