摘要
In this paper we show how to employ the inverse Born-Oppenheimer approximation to establish a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE Rydberg states. The calculations of vibrational and rotational autoionizations of a homonuclear diatomic molecule will be demonstrated as an example. The scaling laws for the autoionization rate constants are determined through nonlinear modeling of the calculated data.
原文 | English |
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文章編號 | 012002 |
期刊 | Journal of Physics: Conference Series |
卷 | 235 |
發行號 | 1 |
DOIs | |
出版狀態 | Published - 2010 |
事件 | International Workshop on Electronic Spectroscopy for Gas-phase Molecules and Solid Surfaces, IWES2009 - Matsushima, 日本 持續時間: 12 10月 2009 → 15 10月 2009 |