Theoretical studies of autoionization dynamics of high Rydberg states

Yi Hsieh Wang*, H. Mineo, S. D. Chao, Yoshiaki Teranishi, S. H. Lin, H. L. Selzle, J. Neusser, E. W. Schlag

*此作品的通信作者

研究成果: Conference article同行評審

摘要

In this paper we show how to employ the inverse Born-Oppenheimer approximation to establish a basis set to study zero kinetic energy (ZEKE) spectroscopy and the autoionization dynamics of the ZEKE Rydberg states. The calculations of vibrational and rotational autoionizations of a homonuclear diatomic molecule will be demonstrated as an example. The scaling laws for the autoionization rate constants are determined through nonlinear modeling of the calculated data.

原文English
文章編號012002
期刊Journal of Physics: Conference Series
235
發行號1
DOIs
出版狀態Published - 2010
事件International Workshop on Electronic Spectroscopy for Gas-phase Molecules and Solid Surfaces, IWES2009 - Matsushima, 日本
持續時間: 12 10月 200915 10月 2009

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