Theoretical foundation of electroabsorption spectroscopy: Self-contained derivation of the basic equations with the direction cosine method and the Euler angle method

Erko Jalviste, Nobuhiro Ohta*

*此作品的通信作者

研究成果: Review article同行評審

57 引文 斯高帕斯(Scopus)

摘要

Self-contained derivation of the electroabsorption (E-A, Stark effect) equations of Liptay and Czekalla, which describe the external electric field effects on absorption spectra of a mobile ensemble of light-absorbing molecules at thermal equilibrium, is reported. Two mathematically different ways for obtaining the ensemble averages, the "direction cosine method" and the "Euler angle method", are compared. Some examples illustrating the application of E-A equations in the analysis of electroabsorption spectra are presented.

原文English
頁(從 - 到)30-46
頁數17
期刊Journal of Photochemistry and Photobiology C: Photochemistry Reviews
8
發行號1
DOIs
出版狀態Published - 3月 2007

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