The dynamics of CO production from the reaction of O(3P) with 1-and 2-butyne

M. E. Umstead; Ming-Chang Lin

doi:10.1016/0301-0104(77)85145-8

The dynamics of CO production from the reaction of O(³P) with 1-and 2-butyne

M. E. Umstead^*, Ming-Chang Lin

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摘要

The reactions of 1and 2butyne with O(³P) were studied at 298 K by means of a CO laser resonant absorption technique. The CO formed. O(³P)+CH₃CH₂CCH→C_C₃H₆H₃CH₂CH+CO. O(³P)+CH₃CCCH₃→CH₃C _C₃H₆CH₃+CO. From the kinetic modeling of the observed rates of CO formation, the rates of these reactions were found to be 5.0 × 10¹¹ and 1.6 × 10¹² ml.

原文	English
頁（從 - 到）	353-359
頁數	7
期刊	Chemical Physics
卷	25
發行號	3
DOIs	https://doi.org/10.1016/0301-0104(77)85145-8
出版狀態	Published - 1 11月 1977

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10.1016/0301-0104(77)85145-8

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title = "The dynamics of CO production from the reaction of O(3P) with 1-and 2-butyne",

abstract = "The reactions of 1and 2butyne with O(3P) were studied at 298 K by means of a CO laser resonant absorption technique. The CO formed. O(3P)+CH3CH2CCH→CC3 H6H3CH2CH+CO. O(3P)+CH3CCCH3→CH3C C3H6CH3+CO. From the kinetic modeling of the observed rates of CO formation, the rates of these reactions were found to be 5.0 × 1011 and 1.6 × 1012 ml.",

author = "Umstead, {M. E.} and Ming-Chang Lin",

year = "1977",

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T1 - The dynamics of CO production from the reaction of O(3P) with 1-and 2-butyne

AU - Umstead, M. E.

AU - Lin, Ming-Chang

PY - 1977/11/1

Y1 - 1977/11/1

N2 - The reactions of 1and 2butyne with O(3P) were studied at 298 K by means of a CO laser resonant absorption technique. The CO formed. O(3P)+CH3CH2CCH→CC3 H6H3CH2CH+CO. O(3P)+CH3CCCH3→CH3C C3H6CH3+CO. From the kinetic modeling of the observed rates of CO formation, the rates of these reactions were found to be 5.0 × 1011 and 1.6 × 1012 ml.

AB - The reactions of 1and 2butyne with O(3P) were studied at 298 K by means of a CO laser resonant absorption technique. The CO formed. O(3P)+CH3CH2CCH→CC3 H6H3CH2CH+CO. O(3P)+CH3CCCH3→CH3C C3H6CH3+CO. From the kinetic modeling of the observed rates of CO formation, the rates of these reactions were found to be 5.0 × 1011 and 1.6 × 1012 ml.

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U2 - 10.1016/0301-0104(77)85145-8

DO - 10.1016/0301-0104(77)85145-8

M3 - Article

AN - SCOPUS:50849152758

SN - 0301-0104

VL - 25

SP - 353

EP - 359

JO - Chemical Physics

JF - Chemical Physics

IS - 3

ER -

The dynamics of CO production from the reaction of O(3P) with 1-and 2-butyne

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The dynamics of CO production from the reaction of O(³P) with 1-and 2-butyne