TY - JOUR
T1 - Temperature–Time Texture Transition of Pb(Zr1−xTix)O3 Thin Films
T2 - I, Role of Pb‐rich Intermediate Phases
AU - Chen, San-Yuan
AU - Chen, I‐Wei ‐W
PY - 1994/1/1
Y1 - 1994/1/1
N2 - Lead‐rich intermediate phases, in particular Pt5–7Pb and PbO, are found to form on Pt(111) atop Ti–buffered Si substrates prior to formation of Pb(Zr1−xTix)O3 (PZT) thin films. Pt5–7Pb is a [111] textured transient intermetallic phase that nucleates PZT[111] texture. PbO is a [001] textured layer compound that nucleates PZT[100] texture. The formation conditions and lattice matching of these intermediate phases have been examined. The presence of other possible intermediate phases, such as pyrochlore and Zr and Ti‐rich phases, has also been investigated but found unrelated to the texture selection of perovskite PZT.
AB - Lead‐rich intermediate phases, in particular Pt5–7Pb and PbO, are found to form on Pt(111) atop Ti–buffered Si substrates prior to formation of Pb(Zr1−xTix)O3 (PZT) thin films. Pt5–7Pb is a [111] textured transient intermetallic phase that nucleates PZT[111] texture. PbO is a [001] textured layer compound that nucleates PZT[100] texture. The formation conditions and lattice matching of these intermediate phases have been examined. The presence of other possible intermediate phases, such as pyrochlore and Zr and Ti‐rich phases, has also been investigated but found unrelated to the texture selection of perovskite PZT.
UR - http://www.scopus.com/inward/record.url?scp=0028514290&partnerID=8YFLogxK
U2 - 10.1111/j.1151-2916.1994.tb04602.x
DO - 10.1111/j.1151-2916.1994.tb04602.x
M3 - Article
AN - SCOPUS:0028514290
SN - 0002-7820
VL - 77
SP - 2332
EP - 2336
JO - Journal of the American Ceramic Society
JF - Journal of the American Ceramic Society
IS - 9
ER -