Synthesis of stable derivatives of C62: The first nonclassical fullerene incorporating a four-membered ring

Wenyuan Qian; Shih-Ching Chuang; Roberto B. Amador; Thibaut Jarrosson; Michael Sander; Susan Pieniazek; Saeed I. Khan; Yves Rubin

doi:10.1021/ja029679s

Synthesis of stable derivatives of C₆₂: The first nonclassical fullerene incorporating a four-membered ring

Wenyuan Qian, Shih-Ching Chuang, Roberto B. Amador, Thibaut Jarrosson, Michael Sander, Susan Pieniazek, Saeed I. Khan, Yves Rubin^*

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摘要

A rational synthetic approach to the first four-membered ring-containing derivatives of C₆₂ is reported. They were synthesized by an inverse electron demand Diels-Alder reaction of 3,6-diaryl-1,2,4,5-tetrazines with C₆₀ in o-dichlorobenzene, followed by visible light irradiation at reflux. The structure of these nonclassical fullerenes derivatives was determined by X-ray single-crystal diffraction.

原文	English
頁（從 - 到）	2066-2067
頁數	2
期刊	Journal of the American Chemical Society
卷	125
發行號	8
DOIs	https://doi.org/10.1021/ja029679s
出版狀態	Published - 26 2月 2003

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10.1021/ja029679s

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abstract = "A rational synthetic approach to the first four-membered ring-containing derivatives of C62 is reported. They were synthesized by an inverse electron demand Diels-Alder reaction of 3,6-diaryl-1,2,4,5-tetrazines with C60 in o-dichlorobenzene, followed by visible light irradiation at reflux. The structure of these nonclassical fullerenes derivatives was determined by X-ray single-crystal diffraction.",

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AU - Qian, Wenyuan

AU - Chuang, Shih-Ching

AU - Amador, Roberto B.

AU - Jarrosson, Thibaut

AU - Sander, Michael

AU - Pieniazek, Susan

AU - Khan, Saeed I.

AU - Rubin, Yves

PY - 2003/2/26

Y1 - 2003/2/26

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AB - A rational synthetic approach to the first four-membered ring-containing derivatives of C62 is reported. They were synthesized by an inverse electron demand Diels-Alder reaction of 3,6-diaryl-1,2,4,5-tetrazines with C60 in o-dichlorobenzene, followed by visible light irradiation at reflux. The structure of these nonclassical fullerenes derivatives was determined by X-ray single-crystal diffraction.

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 8

ER -

Synthesis of stable derivatives of C62: The first nonclassical fullerene incorporating a four-membered ring

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Synthesis of stable derivatives of C₆₂: The first nonclassical fullerene incorporating a four-membered ring