Synthesis of perinaphthenones through rhodium-catalyzed dehydrative annulation of 1-naphthoic acids with alkynes

Takahide Fukuyama*, Taiki Sugimori, Shinji Maetani, Ilhyong Ryu

*此作品的通信作者

研究成果: Article同行評審

16 引文 斯高帕斯(Scopus)

摘要

An efficient approach to the synthesis of perinaphthenones via the rhodium-catalyzed dehydrative annulation of 1-naphthoic acids with internal alkynes was developed. Norbornadiene can act as an acetylene equivalent to give unsubstituted perinaphthenones at the 2- and 3-positions via dehydrative annulation followed by a retro Diels-Alder reaction.

原文English
頁(從 - 到)7583-7587
頁數5
期刊Organic and Biomolecular Chemistry
16
發行號41
DOIs
出版狀態Published - 5 10月 2018

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