TY - JOUR
T1 - Synthesis of 2D PtSe2 Nanolayers on Glass Substrates and Their Integration in Near-Infrared Light Shutters
AU - Minev, Nikolay
AU - Buchkov, Krastyo
AU - Todorova, Nadia
AU - Todorov, Rosen
AU - Videva, Vladimira
AU - Stefanova, Maria
AU - Rafailov, Peter
AU - Karashanova, Daniela
AU - Dikov, Hristosko
AU - Strijkova, Velichka
AU - Trapalis, Christos
AU - Lin, Shiuan Huei
AU - Dimitrov, Dimitre
AU - Marinova, Vera
N1 - Publisher Copyright:
© 2024 The Authors. Published by American Chemical Society.
PY - 2024/4/2
Y1 - 2024/4/2
N2 - PtSe2 has asserted its key role among the emerging 2D transition metal dichalcogenides, however, its simplified growth process with controlled number of layers, high crystalline quality, and on inexpensive substrates is still challenging. Here, we report the synthesis details of PtSe2 layers on soda lime glass substrates by selenization of predeposited Pt layers using the thermally assisted conversion method at atmospheric pressure. PtSe2 syntheses are confirmed by X-ray photoelectron spectroscopy and Raman analysis. The layers were further investigated with transmission electron microscopy and optical ellipsometry, revealing the thickness and its dependence on the metal precursor sputtering time. Finally, the integration of PtSe2 as transparent conductive layers in polymer-dispersed liquid crystal structures operating as near-infrared light shutters is demonstrated and device performance is discussed. The proposed simple and inexpensive synthesis approach opens up new directions toward PtSe2 potential technological applications, including ITO-free optoelectronics.
AB - PtSe2 has asserted its key role among the emerging 2D transition metal dichalcogenides, however, its simplified growth process with controlled number of layers, high crystalline quality, and on inexpensive substrates is still challenging. Here, we report the synthesis details of PtSe2 layers on soda lime glass substrates by selenization of predeposited Pt layers using the thermally assisted conversion method at atmospheric pressure. PtSe2 syntheses are confirmed by X-ray photoelectron spectroscopy and Raman analysis. The layers were further investigated with transmission electron microscopy and optical ellipsometry, revealing the thickness and its dependence on the metal precursor sputtering time. Finally, the integration of PtSe2 as transparent conductive layers in polymer-dispersed liquid crystal structures operating as near-infrared light shutters is demonstrated and device performance is discussed. The proposed simple and inexpensive synthesis approach opens up new directions toward PtSe2 potential technological applications, including ITO-free optoelectronics.
UR - http://www.scopus.com/inward/record.url?scp=85188548189&partnerID=8YFLogxK
U2 - 10.1021/acsomega.3c08235
DO - 10.1021/acsomega.3c08235
M3 - Article
AN - SCOPUS:85188548189
SN - 2470-1343
VL - 9
SP - 14874
EP - 14886
JO - ACS Omega
JF - ACS Omega
IS - 13
ER -