Synthesis of 2D PtSe2 Nanolayers on Glass Substrates and Their Integration in Near-Infrared Light Shutters

Nikolay Minev, Krastyo Buchkov, Nadia Todorova, Rosen Todorov, Vladimira Videva, Maria Stefanova, Peter Rafailov, Daniela Karashanova, Hristosko Dikov, Velichka Strijkova, Christos Trapalis, Shiuan Huei Lin, Dimitre Dimitrov, Vera Marinova*

*此作品的通信作者

研究成果: Article同行評審

摘要

PtSe2 has asserted its key role among the emerging 2D transition metal dichalcogenides, however, its simplified growth process with controlled number of layers, high crystalline quality, and on inexpensive substrates is still challenging. Here, we report the synthesis details of PtSe2 layers on soda lime glass substrates by selenization of predeposited Pt layers using the thermally assisted conversion method at atmospheric pressure. PtSe2 syntheses are confirmed by X-ray photoelectron spectroscopy and Raman analysis. The layers were further investigated with transmission electron microscopy and optical ellipsometry, revealing the thickness and its dependence on the metal precursor sputtering time. Finally, the integration of PtSe2 as transparent conductive layers in polymer-dispersed liquid crystal structures operating as near-infrared light shutters is demonstrated and device performance is discussed. The proposed simple and inexpensive synthesis approach opens up new directions toward PtSe2 potential technological applications, including ITO-free optoelectronics.

原文English
頁(從 - 到)14874-14886
頁數13
期刊ACS Omega
9
發行號13
DOIs
出版狀態Published - 2 4月 2024

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