Synthesis of β-mercuri ketones by the reaction of siloxycyclopropanes with mercuric acetate and their conversion to α-methylene ketones and γ-ketoesters

Ilhyong Ryu*, Koichi Matsumoto, Masato Ando, Shinji Murai, Noboru Sonoda

*此作品的通信作者

研究成果: Article同行評審

61 引文 斯高帕斯(Scopus)

摘要

Siloxycyclopropanes were quantitatively converted to β-acetoxymercuri ketones by the reaction with mercuric acetate. Successive treatment with palladium chloride or palladium chloride/carbon monoxide gave α-methylene ketones or γ-ketoesters, respectively, in good yields.

原文English
頁(從 - 到)4283-4286
頁數4
期刊Tetrahedron Letters
21
發行號44
DOIs
出版狀態Published - 1 1月 1980

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