Strained dehydrobenzoannulenes

Ichiro Hisaki, Motohiro Sonoda, Yoshito Tobe*

*此作品的通信作者

研究成果: Short survey同行評審

63 引文 斯高帕斯(Scopus)

摘要

Dehydrobenzoannulenes (DBAs) have been attracting a great deal of interest as a result of their potential applications as optoelectronic materials, precursors of new forms of carbon materials, and as building blocks for hitherto-unknown 2D carbon networks consisting of sp and sp2 carbon atoms. Among the DBAs, those with substantial strain due to bond-angle deformation at the triple bonds exhibit greater potential as electronic communication units and precursors of new polycyclic, conjugated ring systems owing to their high reactivity towards carbon-carbon bond-forming reactions. It is also of interest to see how the deformation of triple bonds affects the cyclic conjugation of π systems, that is, the aromaticity/antiaromaticity of DBAs. This article reviews these characteristic aspects of strained DBAs.

原文English
頁(從 - 到)833-847
頁數15
期刊European Journal of Organic Chemistry
2006
發行號4
DOIs
出版狀態Published - 13 2月 2006

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