摘要
Dehydrobenzoannulenes (DBAs) have been attracting a great deal of interest as a result of their potential applications as optoelectronic materials, precursors of new forms of carbon materials, and as building blocks for hitherto-unknown 2D carbon networks consisting of sp and sp2 carbon atoms. Among the DBAs, those with substantial strain due to bond-angle deformation at the triple bonds exhibit greater potential as electronic communication units and precursors of new polycyclic, conjugated ring systems owing to their high reactivity towards carbon-carbon bond-forming reactions. It is also of interest to see how the deformation of triple bonds affects the cyclic conjugation of π systems, that is, the aromaticity/antiaromaticity of DBAs. This article reviews these characteristic aspects of strained DBAs.
原文 | English |
---|---|
頁(從 - 到) | 833-847 |
頁數 | 15 |
期刊 | European Journal of Organic Chemistry |
卷 | 2006 |
發行號 | 4 |
DOIs | |
出版狀態 | Published - 13 2月 2006 |