Semiclassical treatment of resonances in the collinear O + HO exchange reaction

Gennady V. Mil'nikov*, Chaoyuan Zhu, Hiroki Nakamura, Vladimir I. Osherov

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2 引文 斯高帕斯(Scopus)

摘要

Feshbach type sharp resonances appearing in the O+HO collinear reaction are analyzed by the newly completed semiclassical theory for the Landau-Zener-Stueckelberg type curve crossings. Not only the resonance positions but also the widths are nicely reproduced in comparison with the exact numerical calculations, even when the widths are as small as 10-8~10-11 au. The semiclassical theory is extended so as to be applicable to the case that the bottom of the upper adiabatic potential is higher than the crossing point.

原文English
頁(從 - 到)448-454
頁數7
期刊Chemical Physics Letters
293
發行號5-6
DOIs
出版狀態Published - 4 九月 1998

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