Selective excitation of deuterium powder patterns for studies of molecular motion in solids

Ta Hsien Lin; Regitze R. Vold

doi:10.1021/j100176a003

Selective excitation of deuterium powder patterns for studies of molecular motion in solids

Ta Hsien Lin, Regitze R. Vold^*

^*此作品的通信作者

醫學系生物化學科

研究成果: Article › 同行評審

15 引文斯高帕斯（Scopus）

摘要

The rate of internal rotation of the amino group in solid p-nitroaniline-N,N-d₂ has been determined from NMR "hole-burning" experiments. This work represents the first use of quantitative simulations of selectively perturbed deuterium powder patterns and the results demonstrate the potential of this technique for characterization of molecular motion in solids.

原文	English
頁（從 - 到）	9032-9034
頁數	3
期刊	Journal of physical chemistry
卷	95
發行號	23
DOIs	https://doi.org/10.1021/j100176a003
出版狀態	Published - 1991

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abstract = "The rate of internal rotation of the amino group in solid p-nitroaniline-N,N-d2 has been determined from NMR {"}hole-burning{"} experiments. This work represents the first use of quantitative simulations of selectively perturbed deuterium powder patterns and the results demonstrate the potential of this technique for characterization of molecular motion in solids.",

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AU - Lin, Ta Hsien

AU - Vold, Regitze R.

PY - 1991

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N2 - The rate of internal rotation of the amino group in solid p-nitroaniline-N,N-d2 has been determined from NMR "hole-burning" experiments. This work represents the first use of quantitative simulations of selectively perturbed deuterium powder patterns and the results demonstrate the potential of this technique for characterization of molecular motion in solids.

AB - The rate of internal rotation of the amino group in solid p-nitroaniline-N,N-d2 has been determined from NMR "hole-burning" experiments. This work represents the first use of quantitative simulations of selectively perturbed deuterium powder patterns and the results demonstrate the potential of this technique for characterization of molecular motion in solids.

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U2 - 10.1021/j100176a003

DO - 10.1021/j100176a003

M3 - Article

AN - SCOPUS:0009977454

SN - 0022-3654

VL - 95

SP - 9032

EP - 9034

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 23

ER -

Selective excitation of deuterium powder patterns for studies of molecular motion in solids

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