Rheological studies of polymers under high pressure carbon dioxide

Maxwell J. Wingert; Jiong Shen; Peter M. Davis; L. James Lee; David L. Tomasko; Kurt W. Koelling

Rheological studies of polymers under high pressure carbon dioxide

Maxwell J. Wingert^*, Jiong Shen, Peter M. Davis, L. James Lee, David L. Tomasko, Kurt W. Koelling

^*此作品的通信作者

生物藥學研究所

研究成果: Paper › 同行評審

2 引文斯高帕斯（Scopus）

摘要

The viscosities of carbon dioxide-impregnated polymers in the literature are currently limited to high shear rates using capillary or extrusion rheometers. This paper uses a rotational rheometer to report data on the zero-shear viscosity of carbon dioxide-saturated polymers. The viscosity drop of a polybutene oil is one and half orders of magnitude at 35°C and 6 MPa, while the zero-shear viscosity of poly(dimethylsiloxane) (PDMS) drops half of an order of magnitude at 30°C and 3 MPa. Efforts are ongoing to measure the CO ₂-plasticized viscosity of polystyrene melt.

原文	English
頁面	291-295
頁數	5
出版狀態	Published - 2005
事件	Society of Plastics Engineers Annual Technical Conference 2005, ANTEC 2005 - Boston, MA, 美國持續時間: 1 5月 2005 → 5 5月 2005

Conference

Conference	Society of Plastics Engineers Annual Technical Conference 2005, ANTEC 2005
國家/地區	美國
城市	Boston, MA
期間	1/05/05 → 5/05/05

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Link to publication in Scopus

引用此

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title = "Rheological studies of polymers under high pressure carbon dioxide",

abstract = "The viscosities of carbon dioxide-impregnated polymers in the literature are currently limited to high shear rates using capillary or extrusion rheometers. This paper uses a rotational rheometer to report data on the zero-shear viscosity of carbon dioxide-saturated polymers. The viscosity drop of a polybutene oil is one and half orders of magnitude at 35°C and 6 MPa, while the zero-shear viscosity of poly(dimethylsiloxane) (PDMS) drops half of an order of magnitude at 30°C and 3 MPa. Efforts are ongoing to measure the CO 2-plasticized viscosity of polystyrene melt.",

keywords = "Carbon dioxide, Plasticization, Polymers, Swelling, Zero-shear viscosity",

author = "Wingert, {Maxwell J.} and Jiong Shen and Davis, {Peter M.} and Lee, {L. James} and Tomasko, {David L.} and Koelling, {Kurt W.}",

year = "2005",

language = "English",

pages = "291--295",

note = "Society of Plastics Engineers Annual Technical Conference 2005, ANTEC 2005 ; Conference date: 01-05-2005 Through 05-05-2005",

}

TY - CONF

T1 - Rheological studies of polymers under high pressure carbon dioxide

AU - Wingert, Maxwell J.

AU - Shen, Jiong

AU - Davis, Peter M.

AU - Lee, L. James

AU - Tomasko, David L.

AU - Koelling, Kurt W.

PY - 2005

Y1 - 2005

N2 - The viscosities of carbon dioxide-impregnated polymers in the literature are currently limited to high shear rates using capillary or extrusion rheometers. This paper uses a rotational rheometer to report data on the zero-shear viscosity of carbon dioxide-saturated polymers. The viscosity drop of a polybutene oil is one and half orders of magnitude at 35°C and 6 MPa, while the zero-shear viscosity of poly(dimethylsiloxane) (PDMS) drops half of an order of magnitude at 30°C and 3 MPa. Efforts are ongoing to measure the CO 2-plasticized viscosity of polystyrene melt.

AB - The viscosities of carbon dioxide-impregnated polymers in the literature are currently limited to high shear rates using capillary or extrusion rheometers. This paper uses a rotational rheometer to report data on the zero-shear viscosity of carbon dioxide-saturated polymers. The viscosity drop of a polybutene oil is one and half orders of magnitude at 35°C and 6 MPa, while the zero-shear viscosity of poly(dimethylsiloxane) (PDMS) drops half of an order of magnitude at 30°C and 3 MPa. Efforts are ongoing to measure the CO 2-plasticized viscosity of polystyrene melt.

KW - Carbon dioxide

KW - Plasticization

KW - Polymers

KW - Swelling

KW - Zero-shear viscosity

UR - http://www.scopus.com/inward/record.url?scp=33644952564&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33644952564

SP - 291

EP - 295

T2 - Society of Plastics Engineers Annual Technical Conference 2005, ANTEC 2005

Y2 - 1 May 2005 through 5 May 2005

ER -

Rheological studies of polymers under high pressure carbon dioxide

摘要

Conference

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