## 摘要

Mixtures of methyl nitrite and 1,3,5-trioxane have been pyrolyzed in shock waves at temperatures between 1180 and 1690 K. The rates of CO production measured by CO laser resonance absorption were kinetically modeled to obtain the rate constant for reaction (9): H + CH_{2}O → CHO + H_{2}. The result from modeling 34 sets of data gave rise to k_{9} = 10^{13.46}exp(— 1879/T)cm^{3}/mole-sec over the entire temperature range studied. A nonlinear least-squares analysis of these high temperature data and all published low temperature (T < 1000K) values led to k_{9} = 10^{8.10}T^{1.62}exp(-1089/T)cm^{3}/mole-sec, covering 260 ≤ T ≤ 1700K.

原文 | English |
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頁（從 - 到） | 19-28 |

頁數 | 10 |

期刊 | Combustion science and technology |

卷 | 64 |

發行號 | 1-3 |

DOIs | |

出版狀態 | Published - 1 3月 1989 |

## 指紋

深入研究「Pyrolysis of Methyl Nitrite and 1,3,5-Trioxane Mixtures in Shock Waves: Kinetic Modeling of the H + CH_{2}O Reaction Rate」主題。共同形成了獨特的指紋。