Pt/titania-nanotube: A potential catalyst for CO2 adsorption and hydrogenation

Kuo Pin Yu; Wen Yueh Yu; Ming Chih Kuo; Yuh Cherng Liou; Shu Hua Chien

doi:10.1016/j.apcatb.2008.03.009

Pt/titania-nanotube: A potential catalyst for CO₂ adsorption and hydrogenation

Kuo Pin Yu, Wen Yueh Yu, Ming Chih Kuo, Yuh Cherng Liou, Shu Hua Chien^*

^*此作品的通信作者

環境與職業衛生研究所

研究成果: Article › 同行評審

121 引文斯高帕斯（Scopus）

摘要

The titania-nanotube-supported Pt (Pt/Tnt) catalyst was prepared by the photochemical deposition of Pt complex on the titania-nanotube (Tnt) synthesized by the alkaline hydrothermal method. The physicochemical properties of Pt/Tnt catalyst were investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, N₂ adsorption and desorption isotherms, temperature-programmed reduction and X-ray photoelectron spectroscopy. The Pt/Tnt catalyst exhibited mixed-valence Pt nanoparticles (1-3 nm) dispersed uniformly on the surface of Tnt with a Brunauer-Emmett-Teller surface area of 187 m²/g. The results of the temperature-programmed desorption of CO₂ indicated the CO₂ adsorption capacity of Tnt was highly enhanced by the supported Pt nanoparticles. In situ Fourier-transform infrared spectroscopy demonstrated that the Pt/Tnt catalyst was highly active for the CO₂ hydrogenation toward methane production at relatively low temperature of 100 °C.

原文	English
頁（從 - 到）	112-118
頁數	7
期刊	Applied Catalysis B: Environmental
卷	84
發行號	1-2
DOIs	https://doi.org/10.1016/j.apcatb.2008.03.009
出版狀態	Published - 25 10月 2008

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10.1016/j.apcatb.2008.03.009

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@article{417ceb618ab94b5ca6d20ec254b3c717,

title = "Pt/titania-nanotube: A potential catalyst for CO2 adsorption and hydrogenation",

abstract = "The titania-nanotube-supported Pt (Pt/Tnt) catalyst was prepared by the photochemical deposition of Pt complex on the titania-nanotube (Tnt) synthesized by the alkaline hydrothermal method. The physicochemical properties of Pt/Tnt catalyst were investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, N2 adsorption and desorption isotherms, temperature-programmed reduction and X-ray photoelectron spectroscopy. The Pt/Tnt catalyst exhibited mixed-valence Pt nanoparticles (1-3 nm) dispersed uniformly on the surface of Tnt with a Brunauer-Emmett-Teller surface area of 187 m2/g. The results of the temperature-programmed desorption of CO2 indicated the CO2 adsorption capacity of Tnt was highly enhanced by the supported Pt nanoparticles. In situ Fourier-transform infrared spectroscopy demonstrated that the Pt/Tnt catalyst was highly active for the CO2 hydrogenation toward methane production at relatively low temperature of 100 °C.",

keywords = "CO hydrogenation, CO-TPD/MS, Pt catalyst, Titania-nanotube",

author = "Yu, {Kuo Pin} and Yu, {Wen Yueh} and Kuo, {Ming Chih} and Liou, {Yuh Cherng} and Chien, {Shu Hua}",

note = "Funding Information: The financial supports from Academia Sinica and the National Science Council of Taiwan, ROC, are gratefully appreciated. We also acknowledge the Instrumentation Center of National Taiwan University for the FE-SEM measurements and the Institute of Physics, Academia Sinica for recording the FE-TEM.",

year = "2008",

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doi = "10.1016/j.apcatb.2008.03.009",

language = "English",

volume = "84",

pages = "112--118",

journal = "Applied Catalysis B: Environmental",

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TY - JOUR

T1 - Pt/titania-nanotube

T2 - A potential catalyst for CO2 adsorption and hydrogenation

AU - Yu, Kuo Pin

AU - Yu, Wen Yueh

AU - Kuo, Ming Chih

AU - Liou, Yuh Cherng

AU - Chien, Shu Hua

N1 - Funding Information: The financial supports from Academia Sinica and the National Science Council of Taiwan, ROC, are gratefully appreciated. We also acknowledge the Instrumentation Center of National Taiwan University for the FE-SEM measurements and the Institute of Physics, Academia Sinica for recording the FE-TEM.

PY - 2008/10/25

Y1 - 2008/10/25

N2 - The titania-nanotube-supported Pt (Pt/Tnt) catalyst was prepared by the photochemical deposition of Pt complex on the titania-nanotube (Tnt) synthesized by the alkaline hydrothermal method. The physicochemical properties of Pt/Tnt catalyst were investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, N2 adsorption and desorption isotherms, temperature-programmed reduction and X-ray photoelectron spectroscopy. The Pt/Tnt catalyst exhibited mixed-valence Pt nanoparticles (1-3 nm) dispersed uniformly on the surface of Tnt with a Brunauer-Emmett-Teller surface area of 187 m2/g. The results of the temperature-programmed desorption of CO2 indicated the CO2 adsorption capacity of Tnt was highly enhanced by the supported Pt nanoparticles. In situ Fourier-transform infrared spectroscopy demonstrated that the Pt/Tnt catalyst was highly active for the CO2 hydrogenation toward methane production at relatively low temperature of 100 °C.

AB - The titania-nanotube-supported Pt (Pt/Tnt) catalyst was prepared by the photochemical deposition of Pt complex on the titania-nanotube (Tnt) synthesized by the alkaline hydrothermal method. The physicochemical properties of Pt/Tnt catalyst were investigated by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, N2 adsorption and desorption isotherms, temperature-programmed reduction and X-ray photoelectron spectroscopy. The Pt/Tnt catalyst exhibited mixed-valence Pt nanoparticles (1-3 nm) dispersed uniformly on the surface of Tnt with a Brunauer-Emmett-Teller surface area of 187 m2/g. The results of the temperature-programmed desorption of CO2 indicated the CO2 adsorption capacity of Tnt was highly enhanced by the supported Pt nanoparticles. In situ Fourier-transform infrared spectroscopy demonstrated that the Pt/Tnt catalyst was highly active for the CO2 hydrogenation toward methane production at relatively low temperature of 100 °C.

KW - CO hydrogenation

KW - CO-TPD/MS

KW - Pt catalyst

KW - Titania-nanotube

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U2 - 10.1016/j.apcatb.2008.03.009

DO - 10.1016/j.apcatb.2008.03.009

M3 - Article

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SN - 0926-3373

VL - 84

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JO - Applied Catalysis B: Environmental

JF - Applied Catalysis B: Environmental

IS - 1-2

ER -

Pt/titania-nanotube: A potential catalyst for CO2 adsorption and hydrogenation

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Pt/titania-nanotube: A potential catalyst for CO₂ adsorption and hydrogenation