Proton-controllable fluorescent switch based on interconversion of polynuclear and dinuclear copper(II) complexes

Hsuch-Ju Liu; Yu Hsin Hung; Chang Chuan Chou; Chan Cheng Su

doi:10.1039/b613583h

Proton-controllable fluorescent switch based on interconversion of polynuclear and dinuclear copper(II) complexes

Hsuch-Ju Liu, Yu Hsin Hung, Chang Chuan Chou^*, Chan Cheng Su

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摘要

The first reversible interconversion process between a one-strand polymeric copper(ii) complex {[Cu₂(L1)₂(ClO₄) ₂](ClO₄)₂}_n (1) and a dicopper(ii) helicate [Cu₂(L1-2H)₂] (2), proceeding via a deprotonation-protonation process, can transduce fluorescence and function as a fluorescent switch simply by introducing a one fiftieth equivalent of coumarine 343 anion, a fluorophore.

原文	English
頁（從 - 到）	495-497
頁數	3
期刊	Chemical Communications
發行號	5
DOIs	https://doi.org/10.1039/b613583h
出版狀態	Published - 30 1月 2007

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abstract = "The first reversible interconversion process between a one-strand polymeric copper(ii) complex {[Cu2(L1)2(ClO4) 2](ClO4)2}n (1) and a dicopper(ii) helicate [Cu2(L1-2H)2] (2), proceeding via a deprotonation-protonation process, can transduce fluorescence and function as a fluorescent switch simply by introducing a one fiftieth equivalent of coumarine 343 anion, a fluorophore.",

author = "Hsuch-Ju Liu and Hung, {Yu Hsin} and Chou, {Chang Chuan} and Su, {Chan Cheng}",

year = "2007",

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AU - Liu, Hsuch-Ju

AU - Hung, Yu Hsin

AU - Chou, Chang Chuan

AU - Su, Chan Cheng

PY - 2007/1/30

Y1 - 2007/1/30

N2 - The first reversible interconversion process between a one-strand polymeric copper(ii) complex {[Cu2(L1)2(ClO4) 2](ClO4)2}n (1) and a dicopper(ii) helicate [Cu2(L1-2H)2] (2), proceeding via a deprotonation-protonation process, can transduce fluorescence and function as a fluorescent switch simply by introducing a one fiftieth equivalent of coumarine 343 anion, a fluorophore.

AB - The first reversible interconversion process between a one-strand polymeric copper(ii) complex {[Cu2(L1)2(ClO4) 2](ClO4)2}n (1) and a dicopper(ii) helicate [Cu2(L1-2H)2] (2), proceeding via a deprotonation-protonation process, can transduce fluorescence and function as a fluorescent switch simply by introducing a one fiftieth equivalent of coumarine 343 anion, a fluorophore.

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U2 - 10.1039/b613583h

DO - 10.1039/b613583h

M3 - Article

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SP - 495

EP - 497

JO - Chemical Communications

JF - Chemical Communications

IS - 5

ER -

Proton-controllable fluorescent switch based on interconversion of polynuclear and dinuclear copper(II) complexes

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