Oxidative decarboxylation of [n.2.2]propellane carboxylic acids with lead tetraacetate. rearrangement approach to bicyclo [n.2.2.]bridgehead alkenes.

Yasuo Sakai*, Shingo Toyotani, Tobe Yoshito, Yoshinobu Odaira

*此作品的通信作者

研究成果: Article同行評審

12 引文 斯高帕斯(Scopus)

摘要

Oxidative decarboxylation of [n.2.2]propellane carboxylic acids (1a-c) with lead tetraacetate gave the bicyclic acetates (2b, c) having a bridgehead double bond and/or the tricyclic acetates (3a, b) in good yields. Vapor phase thermolysis of 3a or 3b afforded the bridgehead olefin 2a or 2b quantatively.

原文English
頁(從 - 到)3855-3856
頁數2
期刊Tetrahedron Letters
20
發行號40
DOIs
出版狀態Published - 1 1月 1979

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