Observation of CH4(v2=1 or v4=1) in the reaction Cl+CH4with time-resolved Fourier-transform infrared absorption spectroscopy

Y. J. Chen, L. K. Chu, S. R. Lin, Yuan-Pern Lee

研究成果: Article同行評審

12 引文 斯高帕斯(Scopus)

摘要

The transient absorption of reaction intermediates in the reaction of methane and chlorine was detected using the Fourier-transform spectrometer. The Cl2, CH4and Ar mixture was found to be in its vibrationally excited state after laser irradiation. Reaction kinetics and rates of quenching of methane were detected. Rates of formation and decay of methane were derived on fitting observed temporal profiles with a simple kinetic model.

原文English
頁(從 - 到)6513-6521
頁數9
期刊Journal of Chemical Physics
115
發行號14
DOIs
出版狀態Published - 8 十月 2001

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