Nucleophilic Conjugate 1,5-Addition of Gilman Reagents to (E)-Hex-2-en-4-ynedioates: An Access to β(γ')-Substituted Muconates

Hung Che Tai, Arjun S. Chavan, Shih-Ching Chuang*

*此作品的通信作者

研究成果: Article同行評審

3 引文 斯高帕斯(Scopus)

摘要

An unusual nucleophilic conjugate addition of organocuprates to enynedioates resulted in chemo- and regioselective formation of β( γ')-addition products, rather than α(δ')-addition products, in moderate to good yields. This addition pattern is different from that with organophosphanes or alkyl amines, and presents a short and efficient method for the preparation of various β(γ')-alkyl- or -aryl-substituted muconates compared with other synthetic approaches.

原文English
文章編號ss-2015-c0211-st
頁(從 - 到)2223-2232
頁數10
期刊Synthesis (Germany)
47
發行號15
DOIs
出版狀態Published - 3 8月 2015

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