Laser photolysis studies on intramolecular exciplex systems of benzophenone and N,N-dimethylaniline

Hiroshi Masuhara; Yasuhiro Maeda; Noboru Mataga; Kyoichi Tomita; Hitoshi Tatemitsu; Yoshiteru Sakata; Soichi Misumi

doi:10.1016/0009-2614(80)80040-6

Laser photolysis studies on intramolecular exciplex systems of benzophenone and N,N-dimethylaniline

Hiroshi Masuhara^*, Yasuhiro Maeda, Noboru Mataga, Kyoichi Tomita, Hitoshi Tatemitsu, Yoshiteru Sakata, Soichi Misumi

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摘要

Photoprimary processes of intramolecular exciplex systems of benzophenone and N,N-dimethylaniline were studied by means of laser spectroscopy. Electron transfer in acetonitrile and hydrogen abstraction in benzene occur quite rapidly almost independent of the number of methylene chain connecting both moieties, which indicates that a definite and restricted structure is not necessary for both processes.

原文	English
頁（從 - 到）	182-184
頁數	3
期刊	Chemical Physics Letters
卷	69
發行號	1
DOIs	https://doi.org/10.1016/0009-2614(80)80040-6
出版狀態	Published - 1 1月 1980

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10.1016/0009-2614(80)80040-6

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AU - Masuhara, Hiroshi

AU - Maeda, Yasuhiro

AU - Mataga, Noboru

AU - Tomita, Kyoichi

AU - Tatemitsu, Hitoshi

AU - Sakata, Yoshiteru

AU - Misumi, Soichi

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Y1 - 1980/1/1

N2 - Photoprimary processes of intramolecular exciplex systems of benzophenone and N,N-dimethylaniline were studied by means of laser spectroscopy. Electron transfer in acetonitrile and hydrogen abstraction in benzene occur quite rapidly almost independent of the number of methylene chain connecting both moieties, which indicates that a definite and restricted structure is not necessary for both processes.

AB - Photoprimary processes of intramolecular exciplex systems of benzophenone and N,N-dimethylaniline were studied by means of laser spectroscopy. Electron transfer in acetonitrile and hydrogen abstraction in benzene occur quite rapidly almost independent of the number of methylene chain connecting both moieties, which indicates that a definite and restricted structure is not necessary for both processes.

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Laser photolysis studies on intramolecular exciplex systems of benzophenone and N,N-dimethylaniline

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