Laser-induced reactions of NO2 in the visible region - II.Kinetic and mechanistic study of the NO2-CO system

M. E. Umstead; S. A. Lloyd; Ming-Chang Lin

doi:10.1007/BF00695593

Laser-induced reactions of NO₂ in the visible region - II.Kinetic and mechanistic study of the NO₂-CO system

M. E. Umstead^*, S. A. Lloyd, Ming-Chang Lin

^*此作品的通信作者

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研究成果: Article › 同行評審

3 引文斯高帕斯（Scopus）

摘要

The 488 nm laser-induced reaction of NO₂ with CO has been investigated and the results computer-modeled. Two reaction mechanisms were considered:1) the direct reaction of vibronically excited NO₂ (NO₂^{* †}) with CO to form CO₂, and 2), the reaction of an intermediate NO₃ radical formed by the reaction of NO₂^{* †} with NO₂ followed by NO₃+CO→NO₂+CO₂. The modeling results strongly support the former as the dominant mechanism.

原文	English
頁（從 - 到）	55-59
頁數	5
期刊	Applied Physics B Photophysics and Laser Chemistry
卷	39
發行號	1
DOIs	https://doi.org/10.1007/BF00695593
出版狀態	Published - 1月 1986

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abstract = "The 488 nm laser-induced reaction of NO2 with CO has been investigated and the results computer-modeled. Two reaction mechanisms were considered:1) the direct reaction of vibronically excited NO2 (NO2* †) with CO to form CO2, and 2), the reaction of an intermediate NO3 radical formed by the reaction of NO2* † with NO2 followed by NO3+CO→NO2+CO2. The modeling results strongly support the former as the dominant mechanism.",

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AU - Lloyd, S. A.

AU - Lin, Ming-Chang

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AB - The 488 nm laser-induced reaction of NO2 with CO has been investigated and the results computer-modeled. Two reaction mechanisms were considered:1) the direct reaction of vibronically excited NO2 (NO2* †) with CO to form CO2, and 2), the reaction of an intermediate NO3 radical formed by the reaction of NO2* † with NO2 followed by NO3+CO→NO2+CO2. The modeling results strongly support the former as the dominant mechanism.

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Laser-induced reactions of NO2 in the visible region - II.Kinetic and mechanistic study of the NO2-CO system

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Laser-induced reactions of NO₂ in the visible region - II.Kinetic and mechanistic study of the NO₂-CO system