Laser-induced reactions of NO2 in the visible region - III. Adamantane nitration in the liquid phase

M. E. Umstead; Ming-Chang Lin

doi:10.1007/BF00695594

Laser-induced reactions of NO₂ in the visible region - III. Adamantane nitration in the liquid phase

M. E. Umstead^*, Ming-Chang Lin

^*此作品的通信作者

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摘要

1-Nitroadamantane was produced by irradiating a solution of adamantane and NO₂ in CCl₄ with the visible lines (457.9-514.5 nm) of an argon-ion laser. At these wavelengths NO₂ does not photodissociate to form O atoms, and thus the nitration reaction must be initiated by another species, probably vibronically excited NO₂ (NO₂ ^*†). The intensity of the laser enables the reaction to be carried out in a reasonable length of time, despite the strong quenching of NO₂ ^*† by CCl₄.

原文	English
頁（從 - 到）	61-63
頁數	3
期刊	Applied Physics B Photophysics and Laser Chemistry
卷	39
發行號	1
DOIs	https://doi.org/10.1007/BF00695594
出版狀態	Published - 1 1月 1986

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abstract = "1-Nitroadamantane was produced by irradiating a solution of adamantane and NO2 in CCl4 with the visible lines (457.9-514.5 nm) of an argon-ion laser. At these wavelengths NO2 does not photodissociate to form O atoms, and thus the nitration reaction must be initiated by another species, probably vibronically excited NO2 (NO2 *†). The intensity of the laser enables the reaction to be carried out in a reasonable length of time, despite the strong quenching of NO2 *† by CCl4.",

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N2 - 1-Nitroadamantane was produced by irradiating a solution of adamantane and NO2 in CCl4 with the visible lines (457.9-514.5 nm) of an argon-ion laser. At these wavelengths NO2 does not photodissociate to form O atoms, and thus the nitration reaction must be initiated by another species, probably vibronically excited NO2 (NO2 *†). The intensity of the laser enables the reaction to be carried out in a reasonable length of time, despite the strong quenching of NO2 *† by CCl4.

AB - 1-Nitroadamantane was produced by irradiating a solution of adamantane and NO2 in CCl4 with the visible lines (457.9-514.5 nm) of an argon-ion laser. At these wavelengths NO2 does not photodissociate to form O atoms, and thus the nitration reaction must be initiated by another species, probably vibronically excited NO2 (NO2 *†). The intensity of the laser enables the reaction to be carried out in a reasonable length of time, despite the strong quenching of NO2 *† by CCl4.

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Laser-induced reactions of NO2 in the visible region - III. Adamantane nitration in the liquid phase

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Laser-induced reactions of NO₂ in the visible region - III. Adamantane nitration in the liquid phase