Laser-induced reactions of NO2 in the visible region - I. Kinetic modeling of nitrobutane formation in the NO2-isobutane system

M. E. Umstead; S. A. Lloyd; J. W. Fleming; Ming-Chang Lin

doi:10.1007/BF00818047

Laser-induced reactions of NO₂ in the visible region - I. Kinetic modeling of nitrobutane formation in the NO₂-isobutane system

M. E. Umstead^*, S. A. Lloyd, J. W. Fleming, Ming-Chang Lin

^*此作品的通信作者

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5 引文斯高帕斯（Scopus）

摘要

The reaction of NO₂ with isobutane, induced by 488 nm laser radiation, to form 2-nitro-2-methylpropane has been investigated and the results computer-modeled according to two possible reaction mechanisms. The first scheme involves the direct abstraction of H from isobutane by vibronically excited NO₂ (NO₂ ^*Δ), and the second, abstraction by an intermediate NO₃ radial produced by NO₂ ^*Δ+NO₂. The modeling results strongly support the NO₂ ^*Δ scheme as the dominant reaction mechanism.

原文	English
頁（從 - 到）	219-224
頁數	6
期刊	Applied Physics B Photophysics and Laser Chemistry
卷	38
發行號	4
DOIs	https://doi.org/10.1007/BF00818047
出版狀態	Published - 1 12月 1985

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abstract = "The reaction of NO2 with isobutane, induced by 488 nm laser radiation, to form 2-nitro-2-methylpropane has been investigated and the results computer-modeled according to two possible reaction mechanisms. The first scheme involves the direct abstraction of H from isobutane by vibronically excited NO2 (NO2 *Δ), and the second, abstraction by an intermediate NO3 radial produced by NO2 *Δ+NO2. The modeling results strongly support the NO2 *Δ scheme as the dominant reaction mechanism.",

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author = "Umstead, {M. E.} and Lloyd, {S. A.} and Fleming, {J. W.} and Ming-Chang Lin",

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AU - Umstead, M. E.

AU - Lloyd, S. A.

AU - Fleming, J. W.

AU - Lin, Ming-Chang

PY - 1985/12/1

Y1 - 1985/12/1

N2 - The reaction of NO2 with isobutane, induced by 488 nm laser radiation, to form 2-nitro-2-methylpropane has been investigated and the results computer-modeled according to two possible reaction mechanisms. The first scheme involves the direct abstraction of H from isobutane by vibronically excited NO2 (NO2 *Δ), and the second, abstraction by an intermediate NO3 radial produced by NO2 *Δ+NO2. The modeling results strongly support the NO2 *Δ scheme as the dominant reaction mechanism.

AB - The reaction of NO2 with isobutane, induced by 488 nm laser radiation, to form 2-nitro-2-methylpropane has been investigated and the results computer-modeled according to two possible reaction mechanisms. The first scheme involves the direct abstraction of H from isobutane by vibronically excited NO2 (NO2 *Δ), and the second, abstraction by an intermediate NO3 radial produced by NO2 *Δ+NO2. The modeling results strongly support the NO2 *Δ scheme as the dominant reaction mechanism.

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JO - Applied Physics B Photophysics and Laser Chemistry

JF - Applied Physics B Photophysics and Laser Chemistry

IS - 4

ER -

Laser-induced reactions of NO2 in the visible region - I. Kinetic modeling of nitrobutane formation in the NO2-isobutane system

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Laser-induced reactions of NO₂ in the visible region - I. Kinetic modeling of nitrobutane formation in the NO₂-isobutane system