Laser-induced reactions of NO2 in the visible region - I. Kinetic modeling of nitrobutane formation in the NO2-isobutane system

M. E. Umstead*, S. A. Lloyd, J. W. Fleming, Ming-Chang Lin

*此作品的通信作者

研究成果: Article同行評審

5 引文 斯高帕斯(Scopus)

摘要

The reaction of NO2 with isobutane, induced by 488 nm laser radiation, to form 2-nitro-2-methylpropane has been investigated and the results computer-modeled according to two possible reaction mechanisms. The first scheme involves the direct abstraction of H from isobutane by vibronically excited NO2 (NO2 ), and the second, abstraction by an intermediate NO3 radial produced by NO2 +NO2. The modeling results strongly support the NO2 scheme as the dominant reaction mechanism.

原文English
頁(從 - 到)219-224
頁數6
期刊Applied Physics B Photophysics and Laser Chemistry
38
發行號4
DOIs
出版狀態Published - 1 十二月 1985

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