Kinetics of CN radical reactions with selected molecules at room temperature

D. A. Lichtin; Ming-Chang Lin

doi:10.1016/0301-0104(85)85109-0

Kinetics of CN radical reactions with selected molecules at room temperature

D. A. Lichtin^*, Ming-Chang Lin

^*此作品的通信作者

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58 引文斯高帕斯（Scopus）

摘要

The two-laser photoinitiation/probe technique has been used to obtain room-temperature second-order rate constants for the reaction of CN radicals with compounds key to atmospheric and combustion chemistry. CN was generated by 266 nm photolysis of ICN. Laser-induced flourescence probing via both CN(A ← X) and CN(B ← X) has been utilized. Values reported are: k(H₂)=(4.9±0.4)×10^-14, k(CH₄)=(1.1±0.1)×10^-12, k(C₂H₆)= (2.9±0.1)×10^-11, k(C₂H₂)=(2.3±0.1) ×10^-10, k(C₂H₄)=(2.7±0.1)×10^-10, k(C₃H₆)=(2.3±0.3)×10^-10, and k(O₂)=(2.5±0.2)×10^-11 cm³ molecule^-1 s^-1. A comparison with available literature data is made and mechanism are discussed.

原文	English
頁（從 - 到）	473-482
頁數	10
期刊	Chemical Physics
卷	96
發行號	3
DOIs	https://doi.org/10.1016/0301-0104(85)85109-0
出版狀態	Published - 1 7月 1985

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title = "Kinetics of CN radical reactions with selected molecules at room temperature",

abstract = "The two-laser photoinitiation/probe technique has been used to obtain room-temperature second-order rate constants for the reaction of CN radicals with compounds key to atmospheric and combustion chemistry. CN was generated by 266 nm photolysis of ICN. Laser-induced flourescence probing via both CN(A ← X) and CN(B ← X) has been utilized. Values reported are: k(H2)=(4.9±0.4)×10-14, k(CH4)=(1.1±0.1)×10-12, k(C2H6)= (2.9±0.1)×10-11, k(C2H2)=(2.3±0.1) ×10-10, k(C2H4)=(2.7±0.1)×10-10, k(C3H6)=(2.3±0.3)×10-10, and k(O2)=(2.5±0.2)×10-11 cm3 molecule-1 s-1. A comparison with available literature data is made and mechanism are discussed.",

author = "Lichtin, \{D. A.\} and Ming-Chang Lin",

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doi = "10.1016/0301-0104(85)85109-0",

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AU - Lichtin, D. A.

AU - Lin, Ming-Chang

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N2 - The two-laser photoinitiation/probe technique has been used to obtain room-temperature second-order rate constants for the reaction of CN radicals with compounds key to atmospheric and combustion chemistry. CN was generated by 266 nm photolysis of ICN. Laser-induced flourescence probing via both CN(A ← X) and CN(B ← X) has been utilized. Values reported are: k(H2)=(4.9±0.4)×10-14, k(CH4)=(1.1±0.1)×10-12, k(C2H6)= (2.9±0.1)×10-11, k(C2H2)=(2.3±0.1) ×10-10, k(C2H4)=(2.7±0.1)×10-10, k(C3H6)=(2.3±0.3)×10-10, and k(O2)=(2.5±0.2)×10-11 cm3 molecule-1 s-1. A comparison with available literature data is made and mechanism are discussed.

AB - The two-laser photoinitiation/probe technique has been used to obtain room-temperature second-order rate constants for the reaction of CN radicals with compounds key to atmospheric and combustion chemistry. CN was generated by 266 nm photolysis of ICN. Laser-induced flourescence probing via both CN(A ← X) and CN(B ← X) has been utilized. Values reported are: k(H2)=(4.9±0.4)×10-14, k(CH4)=(1.1±0.1)×10-12, k(C2H6)= (2.9±0.1)×10-11, k(C2H2)=(2.3±0.1) ×10-10, k(C2H4)=(2.7±0.1)×10-10, k(C3H6)=(2.3±0.3)×10-10, and k(O2)=(2.5±0.2)×10-11 cm3 molecule-1 s-1. A comparison with available literature data is made and mechanism are discussed.

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U2 - 10.1016/0301-0104(85)85109-0

DO - 10.1016/0301-0104(85)85109-0

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AN - SCOPUS:4243580724

SN - 0301-0104

VL - 96

SP - 473

EP - 482

JO - Chemical Physics

JF - Chemical Physics

IS - 3

ER -

Kinetics of CN radical reactions with selected molecules at room temperature

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