TY - JOUR
T1 - Isolation and identification of steroidal saponins in Taiwanese Rhizoma Paridis cultivar (Paris formosana Hayata)
AU - Yang, Deng Jye
AU - Chang, Yan Zin
AU - Liu, Shih Chuan
AU - Lu, Mei Peng
AU - Lin, Jau Tien
PY - 2010/12
Y1 - 2010/12
N2 - Nine steroidal saponins were found in Taiwanese Rhizoma Paridis cultivar (Paris formosana Hayata). They were isolated through liquid-liquid partition and high performance liquid chromatography (HPLC), and identifed by NMR and HPLC-Mass. The nine saponins included three furostanol glycosides: 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl- (1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→2)-O-[α-L-arabinofuranosyl- (1→4)]-β-D-glucopyranoside and 26-O-β-D-glucopyranosyl-22α- methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosy- (1→2)-O-[β-D-glucopyranosyl (1→3)]-β-D-glucopyranoside, two pennogenyl glycosides (spirostanol glycosides): (25R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosy-(1→4)-O-α-L-rhamnopyranosyl- (1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside and (25R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosyl-(1→2)- [α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside, and four diosgenyl glycosides (spirostanol glycosides): (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→4) -O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, (25R)-spirost-5-en-3β-ol (25R)-spirost-5-en-3β-ol 3-O-α-L- rhamnopyranosyl-(1→2)-[β-D-glucopyranoside-(1→3)] -β-D-glucopyranoside, 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L- arabinofuranosyl-(1→4)]-β-D-glucopyranoside and (25R)-spirost-5-en- 3β-ol 3-O-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranoside.
AB - Nine steroidal saponins were found in Taiwanese Rhizoma Paridis cultivar (Paris formosana Hayata). They were isolated through liquid-liquid partition and high performance liquid chromatography (HPLC), and identifed by NMR and HPLC-Mass. The nine saponins included three furostanol glycosides: 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl- (1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, 26-O-β-D-glucopyranosyl-22α-methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosyl-(1→2)-O-[α-L-arabinofuranosyl- (1→4)]-β-D-glucopyranoside and 26-O-β-D-glucopyranosyl-22α- methoxyl-(25R)-furost-5-en-3β, 26-diol 3-O-α-L-rhamnopyranosy- (1→2)-O-[β-D-glucopyranosyl (1→3)]-β-D-glucopyranoside, two pennogenyl glycosides (spirostanol glycosides): (25R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosy-(1→4)-O-α-L-rhamnopyranosyl- (1→4)-O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside and (25R)-spirost-5-en-3β, 17-diol 3-O-α-L-rhamnopyranosyl-(1→2)- [α-L-arabinofuranosyl-(1→4)]-β-D-glucopyranoside, and four diosgenyl glycosides (spirostanol glycosides): (25R)-spirost-5-en-3β-ol 3-O-α-L-rhamnopyranosyl-(1→4)-O-α-L-rhamnopyranosyl-(1→4) -O-[α-L-rhamnopyranosyl-(1→2)]-β-D-glucopyranoside, (25R)-spirost-5-en-3β-ol (25R)-spirost-5-en-3β-ol 3-O-α-L- rhamnopyranosyl-(1→2)-[β-D-glucopyranoside-(1→3)] -β-D-glucopyranoside, 3-O-α-L-rhamnopyranosyl-(1→2)-[α-L- arabinofuranosyl-(1→4)]-β-D-glucopyranoside and (25R)-spirost-5-en- 3β-ol 3-O-α-L-rhamnopyranosyl-(1→2)-O-β-D-glucopyranoside.
KW - Diosgenin
KW - Furostanol glycoside
KW - Paris formosana Hayata
KW - Pennogenin
KW - Rhizoma Paridis
KW - Spirostanol glycoside
UR - http://www.scopus.com/inward/record.url?scp=84870561386&partnerID=8YFLogxK
U2 - 10.6578/TJACFS.2010.034
DO - 10.6578/TJACFS.2010.034
M3 - Article
AN - SCOPUS:84870561386
SN - 1605-2471
VL - 48
SP - 289
EP - 300
JO - Taiwanese Journal of Agricultural Chemistry and Food Science
JF - Taiwanese Journal of Agricultural Chemistry and Food Science
IS - 6
ER -