Ionic photodissociation of poly (N-vinylcarbazole) systems in solution

Hiroshi Masuhara, Satoshi Ohwada, Noboru Mataga, Akira Itaya, Ken Ichi Okamoto, Shigekazu Kusabayashi

研究成果: Article同行評審

4 引文 斯高帕斯(Scopus)

摘要

Ionic photodissociation of poly (N-vinylcarbazole) s quenched by N, N-dimethyltoluidine, 1, 4-dicyanobenzeneand dimethyl terephthalate has been studied in N, N-dimethylformamide. Nanosecond laser photolysisshowed that the dissociation yield decreased as the degree of polymerization increased. The results arediscussed in terms of simple electron donor-acceptor systems. The polymer effect on the ionic photodissociationis concluded to be ascribed to a different dissociative state, slow solvation process and a contribution of geminate recombination.

原文English
頁(從 - 到)275-279
頁數5
期刊KOBUNSHI RONBUNSHU
37
發行號4
DOIs
出版狀態Published - 1 1月 1980

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