Infrared absorption of 2-hydroxyethyl (HOCH2CH2) in solid Ar

Yu Ping Kuo*, Gwo Huei Wann, Yuan-Pern Lee

*此作品的通信作者

研究成果: Article同行評審

14 引文 斯高帕斯(Scopus)

摘要

An argon matrix containing C2H4 and H 2O2 was irradiated at 12 K with the 248 nm emission of a KrF excimer laser; IR spectra were recorded after various periods of photolysis. In addition to lines ascribed to ethylene oxide, acetaldehyde, and vinyl alcohol, absorptions at 2991.0, 2842.7, 1355.4, 1172.5, and 1040.1 cm -1 have been assigned to HOCH2CH2; weaker lines at 3625.8, 2922.4, and 873.9 cm-1 may also be due to HOCH 2CH2. Corresponding lines at 2970.6, 2829.3, 1346.5, 1171.3, and 1020.5 (and probably 3625.8, 2915.1, and 860.7) cm-1 were observed for HO13CH2 13CH2. The results are consistent with ab initio calculations.

原文English
頁(從 - 到)3272-3276
頁數5
期刊The Journal of chemical physics
99
發行號5
DOIs
出版狀態Published - 1 一月 1993

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