High-Rate Hydrogen Generation by Direct Sunlight Irradiation with a Triruthenium Complex

Tung-Kung Wu; Yi Ting Chen; Chun Sheng Peng; Jia Hoa Lin; Jacek Gliniak; Hsin Fang Chan; Chin Hao Chang; Chuen Ru Li; Jen-Shiang K. Yu; Jui Nien Lin

doi:10.1021/acs.inorgchem.8b02888

High-Rate Hydrogen Generation by Direct Sunlight Irradiation with a Triruthenium Complex

Tung-Kung Wu^*, Yi Ting Chen, Chun Sheng Peng, Jia Hoa Lin, Jacek Gliniak, Hsin Fang Chan, Chin Hao Chang, Chuen Ru Li, Jen-Shiang K. Yu, Jui Nien Lin

^*此作品的通信作者

研究成果: Article › 同行評審

3 引文斯高帕斯（Scopus）

摘要

Herein we report a biomimetic triruthenium catalyst that, when under direct sunlight irradiation, facilitates high-rate H₂ production from formic acid (FA) dehydrogenation. The system consists of 2 μmol of catalyst and 6 μmol of tri-o-tolylphosphine in 1 mL of dimethylformamide (DMF) and 4 mL of FA/triethylamine (TEA; 5:2). With 0.4 mM catalyst loaded, a high turnover frequency of 1.15 × 10⁶ h^-1 was detected when under direct sunlight irradiation. In an experiment with 0.2 mM catalyst loaded, more than 140 L of H₂ (280 L of H₂ + CO₂) was produced, and a turnover number of approximately 2.78 × 10⁶ was obtained within 5 h without decline in H₂ generation activity, making it suitable for high-rate H₂ production.

原文	American English
頁（從 - 到）	1967-1975
頁數	9
期刊	Inorganic Chemistry
卷	58
發行號	3
DOIs	https://doi.org/10.1021/acs.inorgchem.8b02888
出版狀態	Published - 4 2月 2019

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10.1021/acs.inorgchem.8b02888

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@article{d8c3e51f9ebd462d9c4131dcc6a16ef5,

title = "High-Rate Hydrogen Generation by Direct Sunlight Irradiation with a Triruthenium Complex",

abstract = "Herein we report a biomimetic triruthenium catalyst that, when under direct sunlight irradiation, facilitates high-rate H2 production from formic acid (FA) dehydrogenation. The system consists of 2 μmol of catalyst and 6 μmol of tri-o-tolylphosphine in 1 mL of dimethylformamide (DMF) and 4 mL of FA/triethylamine (TEA; 5:2). With 0.4 mM catalyst loaded, a high turnover frequency of 1.15 × 106 h-1 was detected when under direct sunlight irradiation. In an experiment with 0.2 mM catalyst loaded, more than 140 L of H2 (280 L of H2 + CO2) was produced, and a turnover number of approximately 2.78 × 106 was obtained within 5 h without decline in H2 generation activity, making it suitable for high-rate H2 production.",

author = "Tung-Kung Wu and Chen, {Yi Ting} and Peng, {Chun Sheng} and Lin, {Jia Hoa} and Jacek Gliniak and Chan, {Hsin Fang} and Chang, {Chin Hao} and Li, {Chuen Ru} and Yu, {Jen-Shiang K.} and Lin, {Jui Nien}",

year = "2019",

month = feb,

day = "4",

doi = "10.1021/acs.inorgchem.8b02888",

language = "American English",

volume = "58",

pages = "1967--1975",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "3",

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TY - JOUR

T1 - High-Rate Hydrogen Generation by Direct Sunlight Irradiation with a Triruthenium Complex

AU - Wu, Tung-Kung

AU - Chen, Yi Ting

AU - Peng, Chun Sheng

AU - Lin, Jia Hoa

AU - Gliniak, Jacek

AU - Chan, Hsin Fang

AU - Chang, Chin Hao

AU - Li, Chuen Ru

AU - Yu, Jen-Shiang K.

AU - Lin, Jui Nien

PY - 2019/2/4

Y1 - 2019/2/4

N2 - Herein we report a biomimetic triruthenium catalyst that, when under direct sunlight irradiation, facilitates high-rate H2 production from formic acid (FA) dehydrogenation. The system consists of 2 μmol of catalyst and 6 μmol of tri-o-tolylphosphine in 1 mL of dimethylformamide (DMF) and 4 mL of FA/triethylamine (TEA; 5:2). With 0.4 mM catalyst loaded, a high turnover frequency of 1.15 × 106 h-1 was detected when under direct sunlight irradiation. In an experiment with 0.2 mM catalyst loaded, more than 140 L of H2 (280 L of H2 + CO2) was produced, and a turnover number of approximately 2.78 × 106 was obtained within 5 h without decline in H2 generation activity, making it suitable for high-rate H2 production.

AB - Herein we report a biomimetic triruthenium catalyst that, when under direct sunlight irradiation, facilitates high-rate H2 production from formic acid (FA) dehydrogenation. The system consists of 2 μmol of catalyst and 6 μmol of tri-o-tolylphosphine in 1 mL of dimethylformamide (DMF) and 4 mL of FA/triethylamine (TEA; 5:2). With 0.4 mM catalyst loaded, a high turnover frequency of 1.15 × 106 h-1 was detected when under direct sunlight irradiation. In an experiment with 0.2 mM catalyst loaded, more than 140 L of H2 (280 L of H2 + CO2) was produced, and a turnover number of approximately 2.78 × 106 was obtained within 5 h without decline in H2 generation activity, making it suitable for high-rate H2 production.

UR - http://www.scopus.com/inward/record.url?scp=85060831430&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.8b02888

DO - 10.1021/acs.inorgchem.8b02888

M3 - Article

C2 - 30676730

AN - SCOPUS:85060831430

SN - 0020-1669

VL - 58

SP - 1967

EP - 1975

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

High-Rate Hydrogen Generation by Direct Sunlight Irradiation with a Triruthenium Complex

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