Evidence for triplet CF2 formation in the O(3P) + C2F4 reaction

David S.Y. Hsu; Ming-Chang Lin

doi:10.1016/0301-0104(77)80017-7

Evidence for triplet CF₂ formation in the O(³P) + C₂F₄ reaction

David S.Y. Hsu, Ming-Chang Lin

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10 引文斯高帕斯（Scopus）

摘要

CO absorption up to υ = 11 was detected in the O(³P) + C₂F₄ reaction. From time-resolved absorption data, the initial vibrational distribution of the CO formed in the reaction was determined. Energetically, the observed population distribution could only be accounted for by the occurrence of the reaction O³P) + triplet CF₂ → CO + F₂ (ΔH⁰ = -89 kcal/mole). A statistical model calculation, based on the assumption of a long-lived CF₂O complex, predicts a CO vibrational distribution that agrees closely with the observed one.

原文	English
頁（從 - 到）	235-238
頁數	4
期刊	Chemical Physics
卷	21
發行號	2
DOIs	https://doi.org/10.1016/0301-0104(77)80017-7
出版狀態	Published - 15 4月 1977

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10.1016/0301-0104(77)80017-7

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title = "Evidence for triplet CF2 formation in the O(3P) + C2F4 reaction",

abstract = "CO absorption up to υ = 11 was detected in the O(3P) + C2F4 reaction. From time-resolved absorption data, the initial vibrational distribution of the CO formed in the reaction was determined. Energetically, the observed population distribution could only be accounted for by the occurrence of the reaction O3P) + triplet CF2 → CO + F2 (ΔH0 = -89 kcal/mole). A statistical model calculation, based on the assumption of a long-lived CF2O complex, predicts a CO vibrational distribution that agrees closely with the observed one.",

author = "Hsu, {David S.Y.} and Ming-Chang Lin",

year = "1977",

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doi = "10.1016/0301-0104(77)80017-7",

language = "English",

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journal = "Chemical Physics",

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T1 - Evidence for triplet CF2 formation in the O(3P) + C2F4 reaction

AU - Hsu, David S.Y.

AU - Lin, Ming-Chang

PY - 1977/4/15

Y1 - 1977/4/15

N2 - CO absorption up to υ = 11 was detected in the O(3P) + C2F4 reaction. From time-resolved absorption data, the initial vibrational distribution of the CO formed in the reaction was determined. Energetically, the observed population distribution could only be accounted for by the occurrence of the reaction O3P) + triplet CF2 → CO + F2 (ΔH0 = -89 kcal/mole). A statistical model calculation, based on the assumption of a long-lived CF2O complex, predicts a CO vibrational distribution that agrees closely with the observed one.

AB - CO absorption up to υ = 11 was detected in the O(3P) + C2F4 reaction. From time-resolved absorption data, the initial vibrational distribution of the CO formed in the reaction was determined. Energetically, the observed population distribution could only be accounted for by the occurrence of the reaction O3P) + triplet CF2 → CO + F2 (ΔH0 = -89 kcal/mole). A statistical model calculation, based on the assumption of a long-lived CF2O complex, predicts a CO vibrational distribution that agrees closely with the observed one.

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U2 - 10.1016/0301-0104(77)80017-7

DO - 10.1016/0301-0104(77)80017-7

M3 - Article

AN - SCOPUS:0038590032

SN - 0301-0104

VL - 21

SP - 235

EP - 238

JO - Chemical Physics

JF - Chemical Physics

IS - 2

ER -

Evidence for triplet CF2 formation in the O(3P) + C2F4 reaction

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Evidence for triplet CF₂ formation in the O(³P) + C₂F₄ reaction