Efficient iridium-catalyzed decarbonylation reaction of aliphatic carboxylic acids leading to internal or terminal alkenes

Shinji Maetani, Takahide Fukuyama*, Nobuyoshi Suzuki, Daisuke Ishihara, Ilhyong Ryu

*此作品的通信作者

研究成果: Article同行評審

47 引文 斯高帕斯(Scopus)

摘要

Vaska's complex, IrCl(CO)(PPh3)2, when combined with KI as an additive, served as an excellent catalyst for the decarbonylation of long-chain aliphatic carboxylic acids to give internal alkenes with high selectivity. On combination with KI and Ac2O as additives under controlled temperatures, decarbonylation proceeded to give terminal alkenes with high selectivity.

原文English
頁(從 - 到)1389-1394
頁數6
期刊Organometallics
30
發行號6
DOIs
出版狀態Published - 28 三月 2011

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