Effects of solute and surfactant addition on the crystallization and morphology of hydroxyapatite powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD)

Hui Ting Chen; Hsin Fang Chang; Horng Huey Ko; I. Ming Hung; Feng Lin Yen; Hong Hsin Huang; Min Husing Hon; Moo Chin Wang; Wei Jen Shih

doi:10.1007/s11661-012-1476-y

Effects of solute and surfactant addition on the crystallization and morphology of hydroxyapatite powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD)

Hui Ting Chen, Hsin Fang Chang, Horng Huey Ko, I. Ming Hung, Feng Lin Yen, Hong Hsin Huang, Min Husing Hon, Moo Chin Wang, Wei Jen Shih

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摘要

The effects of the addition of alcohol and cetyltrimethylammonium bromide (CTAB) on the crystallization and the morphology of hydroxyapatite (HA) powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD) in the 2.5 M NaOH solutions at 348 K (75 C) for 1 hour have been studied. The values of zeta potential have large differences between the sums of DCPD with CTAB (Z _DCPD+CTAB) minus the sum of DCPD and CTAB (Z _DCPD + Z _CTAB), and of HA with CTAB (Z _HA+CTAB) minus the sum of HA and CTAB (Z _HA + Z _CTAB), respectively. When the hydrolysis of DCPD occurred in the 2.5 M NaOH solutions at 348 K (75 C) for 1 hour both with and without alcohol and CTAB, XRD results show the only one phase of HA in the as-dried powders. When the NaOH solution does not contain CTAB, the crystallite size of HA powders decreased from 23 ± 1 to 16 ± 1 nm as the alcohol content was more than 50 pct. The crystallite size of HA powders obtained from DCPD synthesized in the 2.5 M NaOH solution with 1.0 × 10^-3 M CTAB decreased when the alcohol content was increased to 70 pct, whereas the crystallite size increased when the alcohol concentration was greater than that of 70 pct. SEM images show that the HA powders have a rod-like shape when DCPD was synthesized in the 2.5 M NaOH solution without CTAB or alcohol. When the NaOH solution had 1.0 × 10^-3 M CTAB and various alcohol concentrations, the morphology of HA powder still maintained a rod-like or needle-like shape. The HA powder had a maximum specific surface area of 180.25 m²/g when the hydrolysis of DCPD occurred in a 2.5 M NaOH solution containing 1.0 × 10^-3 M CTAB and 70 pct alcohol at 348 K (75 C) for 1 hour.

原文	English
頁（從 - 到）	1023-1033
頁數	11
期刊	Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
卷	44
發行號	2
DOIs	https://doi.org/10.1007/s11661-012-1476-y
出版狀態	Published - 2月 2013

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10.1007/s11661-012-1476-y

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Chen, H. T., Chang, H. F., Ko, H. H., Hung, I. M., Yen, F. L., Huang, H. H., Hon, M. H., Wang, M. C., & Shih, W. J. (2013). Effects of solute and surfactant addition on the crystallization and morphology of hydroxyapatite powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD). Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science, 44(2), 1023-1033. https://doi.org/10.1007/s11661-012-1476-y

@article{74e542bad20d421cb83e836bd40904d9,

title = "Effects of solute and surfactant addition on the crystallization and morphology of hydroxyapatite powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD)",

abstract = "The effects of the addition of alcohol and cetyltrimethylammonium bromide (CTAB) on the crystallization and the morphology of hydroxyapatite (HA) powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD) in the 2.5 M NaOH solutions at 348 K (75 C) for 1 hour have been studied. The values of zeta potential have large differences between the sums of DCPD with CTAB (Z DCPD+CTAB) minus the sum of DCPD and CTAB (Z DCPD + Z CTAB), and of HA with CTAB (Z HA+CTAB) minus the sum of HA and CTAB (Z HA + Z CTAB), respectively. When the hydrolysis of DCPD occurred in the 2.5 M NaOH solutions at 348 K (75 C) for 1 hour both with and without alcohol and CTAB, XRD results show the only one phase of HA in the as-dried powders. When the NaOH solution does not contain CTAB, the crystallite size of HA powders decreased from 23 ± 1 to 16 ± 1 nm as the alcohol content was more than 50 pct. The crystallite size of HA powders obtained from DCPD synthesized in the 2.5 M NaOH solution with 1.0 × 10-3 M CTAB decreased when the alcohol content was increased to 70 pct, whereas the crystallite size increased when the alcohol concentration was greater than that of 70 pct. SEM images show that the HA powders have a rod-like shape when DCPD was synthesized in the 2.5 M NaOH solution without CTAB or alcohol. When the NaOH solution had 1.0 × 10-3 M CTAB and various alcohol concentrations, the morphology of HA powder still maintained a rod-like or needle-like shape. The HA powder had a maximum specific surface area of 180.25 m2/g when the hydrolysis of DCPD occurred in a 2.5 M NaOH solution containing 1.0 × 10-3 M CTAB and 70 pct alcohol at 348 K (75 C) for 1 hour.",

author = "Chen, {Hui Ting} and Chang, {Hsin Fang} and Ko, {Horng Huey} and Hung, {I. Ming} and Yen, {Feng Lin} and Huang, {Hong Hsin} and Hon, {Min Husing} and Wang, {Moo Chin} and Shih, {Wei Jen}",

note = "Funding Information: The authors gratefully acknowledge the financial support of the National Science Council (NSC97-2221-E-037-001-MY3). The authors also wish to thank Mr. H.Y. Yao for TEM experimentation, Mr. F.C. Wu for SEM photography, and Professor M.P. Hung for discussion during the manuscript preparation.",

year = "2013",

month = feb,

doi = "10.1007/s11661-012-1476-y",

language = "English",

volume = "44",

pages = "1023--1033",

journal = "Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science",

issn = "1073-5623",

publisher = "Springer Boston",

number = "2",

}

Chen, HT, Chang, HF, Ko, HH, Hung, IM, Yen, FL, Huang, HH, Hon, MH, Wang, MC & Shih, WJ 2013, 'Effects of solute and surfactant addition on the crystallization and morphology of hydroxyapatite powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD)', Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science, 卷 44, 編號 2, 頁 1023-1033. https://doi.org/10.1007/s11661-012-1476-y

Effects of solute and surfactant addition on the crystallization and morphology of hydroxyapatite powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD). / Chen, Hui Ting; Chang, Hsin Fang; Ko, Horng Huey 等.
於: Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science, 卷 44, 編號 2, 02.2013, p. 1023-1033.

研究成果: Article › 同行評審

TY - JOUR

T1 - Effects of solute and surfactant addition on the crystallization and morphology of hydroxyapatite powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD)

AU - Chen, Hui Ting

AU - Chang, Hsin Fang

AU - Ko, Horng Huey

AU - Hung, I. Ming

AU - Yen, Feng Lin

AU - Huang, Hong Hsin

AU - Hon, Min Husing

AU - Wang, Moo Chin

AU - Shih, Wei Jen

N1 - Funding Information: The authors gratefully acknowledge the financial support of the National Science Council (NSC97-2221-E-037-001-MY3). The authors also wish to thank Mr. H.Y. Yao for TEM experimentation, Mr. F.C. Wu for SEM photography, and Professor M.P. Hung for discussion during the manuscript preparation.

PY - 2013/2

Y1 - 2013/2

N2 - The effects of the addition of alcohol and cetyltrimethylammonium bromide (CTAB) on the crystallization and the morphology of hydroxyapatite (HA) powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD) in the 2.5 M NaOH solutions at 348 K (75 C) for 1 hour have been studied. The values of zeta potential have large differences between the sums of DCPD with CTAB (Z DCPD+CTAB) minus the sum of DCPD and CTAB (Z DCPD + Z CTAB), and of HA with CTAB (Z HA+CTAB) minus the sum of HA and CTAB (Z HA + Z CTAB), respectively. When the hydrolysis of DCPD occurred in the 2.5 M NaOH solutions at 348 K (75 C) for 1 hour both with and without alcohol and CTAB, XRD results show the only one phase of HA in the as-dried powders. When the NaOH solution does not contain CTAB, the crystallite size of HA powders decreased from 23 ± 1 to 16 ± 1 nm as the alcohol content was more than 50 pct. The crystallite size of HA powders obtained from DCPD synthesized in the 2.5 M NaOH solution with 1.0 × 10-3 M CTAB decreased when the alcohol content was increased to 70 pct, whereas the crystallite size increased when the alcohol concentration was greater than that of 70 pct. SEM images show that the HA powders have a rod-like shape when DCPD was synthesized in the 2.5 M NaOH solution without CTAB or alcohol. When the NaOH solution had 1.0 × 10-3 M CTAB and various alcohol concentrations, the morphology of HA powder still maintained a rod-like or needle-like shape. The HA powder had a maximum specific surface area of 180.25 m2/g when the hydrolysis of DCPD occurred in a 2.5 M NaOH solution containing 1.0 × 10-3 M CTAB and 70 pct alcohol at 348 K (75 C) for 1 hour.

AB - The effects of the addition of alcohol and cetyltrimethylammonium bromide (CTAB) on the crystallization and the morphology of hydroxyapatite (HA) powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD) in the 2.5 M NaOH solutions at 348 K (75 C) for 1 hour have been studied. The values of zeta potential have large differences between the sums of DCPD with CTAB (Z DCPD+CTAB) minus the sum of DCPD and CTAB (Z DCPD + Z CTAB), and of HA with CTAB (Z HA+CTAB) minus the sum of HA and CTAB (Z HA + Z CTAB), respectively. When the hydrolysis of DCPD occurred in the 2.5 M NaOH solutions at 348 K (75 C) for 1 hour both with and without alcohol and CTAB, XRD results show the only one phase of HA in the as-dried powders. When the NaOH solution does not contain CTAB, the crystallite size of HA powders decreased from 23 ± 1 to 16 ± 1 nm as the alcohol content was more than 50 pct. The crystallite size of HA powders obtained from DCPD synthesized in the 2.5 M NaOH solution with 1.0 × 10-3 M CTAB decreased when the alcohol content was increased to 70 pct, whereas the crystallite size increased when the alcohol concentration was greater than that of 70 pct. SEM images show that the HA powders have a rod-like shape when DCPD was synthesized in the 2.5 M NaOH solution without CTAB or alcohol. When the NaOH solution had 1.0 × 10-3 M CTAB and various alcohol concentrations, the morphology of HA powder still maintained a rod-like or needle-like shape. The HA powder had a maximum specific surface area of 180.25 m2/g when the hydrolysis of DCPD occurred in a 2.5 M NaOH solution containing 1.0 × 10-3 M CTAB and 70 pct alcohol at 348 K (75 C) for 1 hour.

UR - http://www.scopus.com/inward/record.url?scp=84877578696&partnerID=8YFLogxK

U2 - 10.1007/s11661-012-1476-y

DO - 10.1007/s11661-012-1476-y

M3 - Article

AN - SCOPUS:84877578696

SN - 1073-5623

VL - 44

SP - 1023

EP - 1033

JO - Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science

JF - Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science

IS - 2

ER -

Chen HT, Chang HF, Ko HH, Hung IM, Yen FL, Huang HH 等. Effects of solute and surfactant addition on the crystallization and morphology of hydroxyapatite powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD). Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science. 2013 2月;44(2):1023-1033. doi: 10.1007/s11661-012-1476-y

Effects of solute and surfactant addition on the crystallization and morphology of hydroxyapatite powders synthesized by hydrolysis of calcium hydrogen phosphate dehydrate (DCPD)

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