Effect of polyaniline surface modification of carbon nanofibers on cure kinetics of epoxy resin

Zhi Qi Cai; Siva Movva; Nan Rong Chiou; Dante Guerra; Yunior Hioe; Jose M. Castro; L. James Lee

doi:10.1002/app.31656

Effect of polyaniline surface modification of carbon nanofibers on cure kinetics of epoxy resin

Zhi Qi Cai, Siva Movva, Nan Rong Chiou, Dante Guerra, Yunior Hioe, Jose M. Castro, L. James Lee

生物藥學研究所

研究成果: Article › 同行評審

12 引文斯高帕斯（Scopus）

摘要

Polyaniline (PANI) "nanograss" was grown on carbon nanofibers (CNFs). The cure behavior of an epoxy resin with and without unmodified CNFs or PANI modified CNFs was studied by means of non-isothermal and isothermal differential scanning calorimetry (DSC). CNFs accelerated the reaction of epoxy and diamine. PANI surface modification further increased the reaction rate and the extent of reaction. An autocatalytic cure kinetic model was used to fit the reaction curves. It was found that activation energies of the epoxy reaction decreased in the presence of CNFs and PANI modified CNFs. The observed catalytic effect of CNF and PANI surface coating can be very useful for low temperature cure of large epoxy composite products.

原文	English
頁（從 - 到）	2328-2335
頁數	8
期刊	Journal of Applied Polymer Science
卷	118
發行號	4
DOIs	https://doi.org/10.1002/app.31656
出版狀態	Published - 15 11月 2010

存取文件

10.1002/app.31656

其它文件與鏈接

Link to publication in Scopus

引用此

@article{0c8ab31bc8e848fda293d6c9aaa1d24d,

title = "Effect of polyaniline surface modification of carbon nanofibers on cure kinetics of epoxy resin",

abstract = "Polyaniline (PANI) {"}nanograss{"} was grown on carbon nanofibers (CNFs). The cure behavior of an epoxy resin with and without unmodified CNFs or PANI modified CNFs was studied by means of non-isothermal and isothermal differential scanning calorimetry (DSC). CNFs accelerated the reaction of epoxy and diamine. PANI surface modification further increased the reaction rate and the extent of reaction. An autocatalytic cure kinetic model was used to fit the reaction curves. It was found that activation energies of the epoxy reaction decreased in the presence of CNFs and PANI modified CNFs. The observed catalytic effect of CNF and PANI surface coating can be very useful for low temperature cure of large epoxy composite products.",

keywords = "Carbon nanofibers (CNFs), Cure behavior, Epoxy resin, Polyaniline",

author = "Cai, {Zhi Qi} and Siva Movva and Chiou, {Nan Rong} and Dante Guerra and Yunior Hioe and Castro, {Jose M.} and Lee, {L. James}",

year = "2010",

month = nov,

day = "15",

doi = "10.1002/app.31656",

language = "English",

volume = "118",

pages = "2328--2335",

journal = "Journal of Applied Polymer Science",

issn = "0021-8995",

publisher = "John Wiley and Sons Inc.",

number = "4",

}

TY - JOUR

T1 - Effect of polyaniline surface modification of carbon nanofibers on cure kinetics of epoxy resin

AU - Cai, Zhi Qi

AU - Movva, Siva

AU - Chiou, Nan Rong

AU - Guerra, Dante

AU - Hioe, Yunior

AU - Castro, Jose M.

AU - Lee, L. James

PY - 2010/11/15

Y1 - 2010/11/15

N2 - Polyaniline (PANI) "nanograss" was grown on carbon nanofibers (CNFs). The cure behavior of an epoxy resin with and without unmodified CNFs or PANI modified CNFs was studied by means of non-isothermal and isothermal differential scanning calorimetry (DSC). CNFs accelerated the reaction of epoxy and diamine. PANI surface modification further increased the reaction rate and the extent of reaction. An autocatalytic cure kinetic model was used to fit the reaction curves. It was found that activation energies of the epoxy reaction decreased in the presence of CNFs and PANI modified CNFs. The observed catalytic effect of CNF and PANI surface coating can be very useful for low temperature cure of large epoxy composite products.

AB - Polyaniline (PANI) "nanograss" was grown on carbon nanofibers (CNFs). The cure behavior of an epoxy resin with and without unmodified CNFs or PANI modified CNFs was studied by means of non-isothermal and isothermal differential scanning calorimetry (DSC). CNFs accelerated the reaction of epoxy and diamine. PANI surface modification further increased the reaction rate and the extent of reaction. An autocatalytic cure kinetic model was used to fit the reaction curves. It was found that activation energies of the epoxy reaction decreased in the presence of CNFs and PANI modified CNFs. The observed catalytic effect of CNF and PANI surface coating can be very useful for low temperature cure of large epoxy composite products.

KW - Carbon nanofibers (CNFs)

KW - Cure behavior

KW - Epoxy resin

KW - Polyaniline

UR - http://www.scopus.com/inward/record.url?scp=77956426753&partnerID=8YFLogxK

U2 - 10.1002/app.31656

DO - 10.1002/app.31656

M3 - Article

AN - SCOPUS:77956426753

SN - 0021-8995

VL - 118

SP - 2328

EP - 2335

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 4

ER -

Effect of polyaniline surface modification of carbon nanofibers on cure kinetics of epoxy resin

摘要

存取文件

其它文件與鏈接

指紋

引用此