Effect of ball-milling solvent on the decomposition properties of Ba(Pb 1-x Bi x )O 3

M. C. Chang; J. M. Wu; S. Y. Cheng; San-Yuan Chen

doi:10.1016/S0254-0584(00)00400-4

Effect of ball-milling solvent on the decomposition properties of Ba(Pb _1-x Bi _x )O ₃

M. C. Chang^*, J. M. Wu, S. Y. Cheng, San-Yuan Chen

^*此作品的通信作者

材料科學與工程學系

研究成果: Article › 同行評審

4 引文斯高帕斯（Scopus）

摘要

Ba(Pb_1-xBi_x)O₃ compound, which exhibits perovskite structure is a superconducting material. It can be a useful material for resistor when x value equals 0. The conducting behavior of BaPbO₃ is liable to be affected during aqueous processing. In contrast, the phenomenon is not found in Ba(Pb_0.8Bi_0.2)O₃. The milling solvents of water and ethanol have different effect on the stability of perovskite phase. The decomposition of BaPbO₃ into BaCO₃ and PbO₂ is found when CO₃^2- ion exists. The partial substitution of Bi³⁺ stabilizes the perovskite phase. The stabilization and decomposition of perovskite phase explain the resistivity change with different milling solvents.

原文	English
頁（從 - 到）	226-229
頁數	4
期刊	Materials Chemistry and Physics
卷	69
發行號	1-3
DOIs	https://doi.org/10.1016/S0254-0584(00)00400-4
出版狀態	Published - 1 3月 2001

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10.1016/S0254-0584(00)00400-4

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title = "Effect of ball-milling solvent on the decomposition properties of Ba(Pb 1-x Bi x )O 3",

abstract = "Ba(Pb1-xBix)O3 compound, which exhibits perovskite structure is a superconducting material. It can be a useful material for resistor when x value equals 0. The conducting behavior of BaPbO3 is liable to be affected during aqueous processing. In contrast, the phenomenon is not found in Ba(Pb0.8Bi0.2)O3. The milling solvents of water and ethanol have different effect on the stability of perovskite phase. The decomposition of BaPbO3 into BaCO3 and PbO2 is found when CO32- ion exists. The partial substitution of Bi3+ stabilizes the perovskite phase. The stabilization and decomposition of perovskite phase explain the resistivity change with different milling solvents.",

keywords = "Ba(Pb1−xBix)O3, Perovskite, Solvent, Decomposition",

author = "Chang, {M. C.} and Wu, {J. M.} and Cheng, {S. Y.} and San-Yuan Chen",

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AU - Chang, M. C.

AU - Wu, J. M.

AU - Cheng, S. Y.

AU - Chen, San-Yuan

PY - 2001/3/1

Y1 - 2001/3/1

N2 - Ba(Pb1-xBix)O3 compound, which exhibits perovskite structure is a superconducting material. It can be a useful material for resistor when x value equals 0. The conducting behavior of BaPbO3 is liable to be affected during aqueous processing. In contrast, the phenomenon is not found in Ba(Pb0.8Bi0.2)O3. The milling solvents of water and ethanol have different effect on the stability of perovskite phase. The decomposition of BaPbO3 into BaCO3 and PbO2 is found when CO32- ion exists. The partial substitution of Bi3+ stabilizes the perovskite phase. The stabilization and decomposition of perovskite phase explain the resistivity change with different milling solvents.

AB - Ba(Pb1-xBix)O3 compound, which exhibits perovskite structure is a superconducting material. It can be a useful material for resistor when x value equals 0. The conducting behavior of BaPbO3 is liable to be affected during aqueous processing. In contrast, the phenomenon is not found in Ba(Pb0.8Bi0.2)O3. The milling solvents of water and ethanol have different effect on the stability of perovskite phase. The decomposition of BaPbO3 into BaCO3 and PbO2 is found when CO32- ion exists. The partial substitution of Bi3+ stabilizes the perovskite phase. The stabilization and decomposition of perovskite phase explain the resistivity change with different milling solvents.

KW - Ba(Pb1−xBix)O3

KW - Perovskite

KW - Solvent

KW - Decomposition

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U2 - 10.1016/S0254-0584(00)00400-4

DO - 10.1016/S0254-0584(00)00400-4

M3 - Article

AN - SCOPUS:0035281620

SN - 0254-0584

VL - 69

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EP - 229

JO - Materials Chemistry and Physics

JF - Materials Chemistry and Physics

IS - 1-3

ER -

Effect of ball-milling solvent on the decomposition properties of Ba(Pb 1-x Bi x )O 3

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Effect of ball-milling solvent on the decomposition properties of Ba(Pb _1-x Bi _x )O ₃