Dynamics of reactions of O(3P) atoms with 1-alkynes as studied by a CO laser resonance absorption technique

W. M. Shaub; T. L. Burks; Ming-Chang Lin

doi:10.1016/0301-0104(80)87014-5

Dynamics of reactions of O(³P) atoms with 1-alkynes as studied by a CO laser resonance absorption technique

W. M. Shaub^*, T. L. Burks, Ming-Chang Lin

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摘要

We have studied the reactions of O(³P) atoms with alkynes in the series acetylene through 1-hexyne at room temperature via the CO laser resonance absorption technique. Observed vibrational population distributions of the CO product were found to be consistent with the general mechanism: {A figure is presented} Based on the measured CO′ product yields, the rate constants or O(³P) + 1-pentyne and 1-hexyne have been evaluated.

原文	English
頁（從 - 到）	455-460
頁數	6
期刊	Chemical Physics
卷	45
發行號	3
DOIs	https://doi.org/10.1016/0301-0104(80)87014-5
出版狀態	Published - 1 2月 1980

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10.1016/0301-0104(80)87014-5

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abstract = "We have studied the reactions of O(3P) atoms with alkynes in the series acetylene through 1-hexyne at room temperature via the CO laser resonance absorption technique. Observed vibrational population distributions of the CO product were found to be consistent with the general mechanism: {A figure is presented} Based on the measured CO′ product yields, the rate constants or O(3P) + 1-pentyne and 1-hexyne have been evaluated.",

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N2 - We have studied the reactions of O(3P) atoms with alkynes in the series acetylene through 1-hexyne at room temperature via the CO laser resonance absorption technique. Observed vibrational population distributions of the CO product were found to be consistent with the general mechanism: {A figure is presented} Based on the measured CO′ product yields, the rate constants or O(3P) + 1-pentyne and 1-hexyne have been evaluated.

AB - We have studied the reactions of O(3P) atoms with alkynes in the series acetylene through 1-hexyne at room temperature via the CO laser resonance absorption technique. Observed vibrational population distributions of the CO product were found to be consistent with the general mechanism: {A figure is presented} Based on the measured CO′ product yields, the rate constants or O(3P) + 1-pentyne and 1-hexyne have been evaluated.

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ER -

Dynamics of reactions of O(3P) atoms with 1-alkynes as studied by a CO laser resonance absorption technique

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Dynamics of reactions of O(³P) atoms with 1-alkynes as studied by a CO laser resonance absorption technique