Dimethyldicyanosilane: A Reagent for Concurrent Silylation and Cyanosilylation of. β-Diketones

Ilhyong Ryu; Shinji Murai; Akiko Shinonaga; Tetsuro Horiike; Noboru Sonoda

doi:10.1021/jo00398a075

Dimethyldicyanosilane: A Reagent for Concurrent Silylation and Cyanosilylation of. β-Diketones

Ilhyong Ryu, Shinji Murai^*, Akiko Shinonaga, Tetsuro Horiike, Noboru Sonoda

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摘要

Six-membered rings (5-cyano-2,6-dioxa-l-sila-cyclohex-3-enes) are obtained by the reaction of β-diketones with dimethyldicyanosilane in which concurrent silylation and cyanosilylation of the two carbonyl groups of β-diketones occur.

原文	English
頁（從 - 到）	780-782
頁數	3
期刊	Journal of Organic Chemistry
卷	43
發行號	4
DOIs	https://doi.org/10.1021/jo00398a075
出版狀態	Published - 1 1月 1978

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10.1021/jo00398a075

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title = "Dimethyldicyanosilane: A Reagent for Concurrent Silylation and Cyanosilylation of. β-Diketones",

abstract = "Six-membered rings (5-cyano-2,6-dioxa-l-sila-cyclohex-3-enes) are obtained by the reaction of β-diketones with dimethyldicyanosilane in which concurrent silylation and cyanosilylation of the two carbonyl groups of β-diketones occur.",

author = "Ilhyong Ryu and Shinji Murai and Akiko Shinonaga and Tetsuro Horiike and Noboru Sonoda",

year = "1978",

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journal = "Journal of Organic Chemistry",

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T1 - Dimethyldicyanosilane

T2 - A Reagent for Concurrent Silylation and Cyanosilylation of. β-Diketones

AU - Ryu, Ilhyong

AU - Murai, Shinji

AU - Shinonaga, Akiko

AU - Horiike, Tetsuro

AU - Sonoda, Noboru

PY - 1978/1/1

Y1 - 1978/1/1

N2 - Six-membered rings (5-cyano-2,6-dioxa-l-sila-cyclohex-3-enes) are obtained by the reaction of β-diketones with dimethyldicyanosilane in which concurrent silylation and cyanosilylation of the two carbonyl groups of β-diketones occur.

AB - Six-membered rings (5-cyano-2,6-dioxa-l-sila-cyclohex-3-enes) are obtained by the reaction of β-diketones with dimethyldicyanosilane in which concurrent silylation and cyanosilylation of the two carbonyl groups of β-diketones occur.

UR - http://www.scopus.com/inward/record.url?scp=0042511297&partnerID=8YFLogxK

U2 - 10.1021/jo00398a075

DO - 10.1021/jo00398a075

M3 - Letter

AN - SCOPUS:0042511297

VL - 43

SP - 780

EP - 782

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 4

ER -

Dimethyldicyanosilane: A Reagent for Concurrent Silylation and Cyanosilylation of. β-Diketones

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