Benzimidazolone-Dioxazine Pigments-Based Conjugated Polymers for Organic Field-Effect Transistor

Wei Yao Tung, Cheng Pu, Yi Fan Huang, Wei Xie, Chung Fu Cheng, Yun Yu Lai, Xiang Li, Heng Yi Lin, Yueh Ting Lai, Kun Chen, Chien Lung Wang, Yu Zhu*

*此作品的通信作者

研究成果: Article同行評審

摘要

Molecules based on benzimidazolone-dioxazine are known as blue/violet pigments and have been commercialized for decades. However, unfavorable solubility limits the application of these structures as building blocks of conjugated polymers despite their low band gaps. Herein, a series of donor–acceptor conjugated polymers containing soluble benzimidazolone-dioxazine structures as the acceptors and oligothiophene as donors are synthesized and investigated. With increasing numbers of thiophene rings, the steric hindrance diminishes and high molecular weight polymers can be achieved, leading to an improved performance in organic field effect transistor devices. The hole mobility of polymers with three to six thiophene units is on the order of 10−1 cm2 V−1 s −1. Among all the polymers, polymer P3 with three thiophene units between benzimidazolone-dioxazine structures shows the best hole mobility of 0.4 cm2 V−1 s −1. Grazing-incidence wide-angle X-ray scattering results reveal that the high mobility of organic field-effect transistors (OFETs) can be accredited by matched donor–acceptor packing in the solid thin films.

原文English
期刊Macromolecular Rapid Communications
DOIs
出版狀態Accepted/In press - 2022

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