Asymmetric Homogeneity and Transport Properties of Isotropic Copper-Based Ternary Chalcogenides

Wan Ting Yen, Hsin Jay Wu*

*此作品的通信作者

研究成果: Article同行評審

摘要

This research delves into the copper-based chalcogenides, unveiling the synthesis and characterization of two stable ternary copper chalcogenides, Cu5Se7Te3 and Cu6SeTe3, at 523 K. An isothermal section of Cu-Se-Te constructed through the detailed analysis upon the postannealed alloys has brought a comprehensive understanding to the homogeneity of these compounds. The Cu6SeTe3, located near the Cu2(Se, Te) solid solution, showcases an asymmetric compositional region extending from chemically stoichiometric Cu6Se2Te2 to off-stoichiometric Cu6SeTe3. Structure refinement from the single-crystal X-ray diffraction has confirmed the cubic symmetry of Cu6SeTe3, yet the Te atoms deviate from the expected position. In the cubic lattice composed of orderly arranged selenium and tellurium, copper ions behave like a liquid at high temperatures, which is characteristic of phonon-liquid electron-crystal (PLEC) chalcogenides. Cu6SeTe3 and Cu6Se2Te2 show no phase transitions between 100 and 600 K, signifying their thermal stability in practical use. Moreover, Cu6Se2Te2 reached an ideal carrier concentration of 6 × 1019 cm-3, alongside an enhancement in the power factor and a decrease in thermal conductivity than the Te-rich Cu6SeTe3. These composition adjustments in the Cu6SeTe3 phase also raise the Z value.

原文English
頁(從 - 到)5285-5291
頁數7
期刊ACS Applied Energy Materials
7
發行號12
DOIs
出版狀態Published - 24 6月 2024

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