Aryl λ3-Iodane-Mediated 6-exo-trig Cyclization to Synthesize Highly Substituted Chiral Morpholines

Jaya Kishorevandavasi, Wan Ping Hu, Gopal Chandrusenadi, Hui Ting Chen, Hsing Yin Chen, Kuang Chan Hsieh, Jeh Jeng Wang*

*此作品的通信作者

研究成果: Article同行評審

10 引文 斯高帕斯(Scopus)

摘要

A mild and efficient transition metal-free approach has been developed for the synthesis of highly substituted chiral morpholines from alkenols by amino acid-derived iodine(III) reagents via a 6-exo-trig cyclization. The key features of this work include the formation of three chiral centers with a high diastereomeric ratio, broad functional group compatibility, and atom/time economic methodology.

原文English
頁(從 - 到)2788-2794
頁數7
期刊Advanced Synthesis and Catalysis
357
發行號13
DOIs
出版狀態Published - 1 9月 2015

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