Approaches to size-selective formation of fullerenes by cyclization of highly reactive polyyne chains

Rui Umeda; Motohiro Sonoda; Tomonari Wakabayashi; Yoshito Tobe

doi:10.1246/cl.2005.1574

Approaches to size-selective formation of fullerenes by cyclization of highly reactive polyyne chains

Rui Umeda, Motohiro Sonoda, Tomonari Wakabayashi, Yoshito Tobe^*

^*此作品的通信作者

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研究成果: Review article › 同行評審

5 引文斯高帕斯（Scopus）

摘要

As an approach to size-selective formation of fullerenes, we developed a method based on the cyclization of reactive cyclic polyynes which were generated by [2 + 2] cycloreversion of [4.3.2]propellatriene units. This method was proven to work successfully for the first time for the formation of fullerene ions C₆₀⁺ and C₆₀^- in the gas phase. This protocol is useful for generation of a small three-dimensional carbon cluster ion C₃₆^- and a large fullerene C₇₈ ^-, as well.

原文	English
頁（從 - 到）	1574-1579
頁數	6
期刊	Chemistry Letters
卷	34
發行號	12
DOIs	https://doi.org/10.1246/cl.2005.1574
出版狀態	Published - 5 12月 2005

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AU - Umeda, Rui

AU - Sonoda, Motohiro

AU - Wakabayashi, Tomonari

AU - Tobe, Yoshito

PY - 2005/12/5

Y1 - 2005/12/5

N2 - As an approach to size-selective formation of fullerenes, we developed a method based on the cyclization of reactive cyclic polyynes which were generated by [2 + 2] cycloreversion of [4.3.2]propellatriene units. This method was proven to work successfully for the first time for the formation of fullerene ions C60+ and C60- in the gas phase. This protocol is useful for generation of a small three-dimensional carbon cluster ion C36- and a large fullerene C78 -, as well.

AB - As an approach to size-selective formation of fullerenes, we developed a method based on the cyclization of reactive cyclic polyynes which were generated by [2 + 2] cycloreversion of [4.3.2]propellatriene units. This method was proven to work successfully for the first time for the formation of fullerene ions C60+ and C60- in the gas phase. This protocol is useful for generation of a small three-dimensional carbon cluster ion C36- and a large fullerene C78 -, as well.

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DO - 10.1246/cl.2005.1574

M3 - Review article

AN - SCOPUS:33644552450

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SP - 1574

EP - 1579

JO - Chemistry Letters

JF - Chemistry Letters

IS - 12

ER -

Approaches to size-selective formation of fullerenes by cyclization of highly reactive polyyne chains

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