An Unusual Simmons-Smith Reaction Affording Noncyclopropyl Compounds. New Route to 2-Methylenecycloalkanols from Silyl Alkenyl Ethers

Shinji Murai*, Tomoyuki Aya, Tsumoru Renge, Ilhyong Ryu, Noboru Sonoda

*此作品的通信作者

研究成果: Letter同行評審

32 引文 斯高帕斯(Scopus)

摘要

Reaction of silyl cycloalkenyl ethers under a certain Simmons-Smith reaction conditions gives silyl ethers of 2-methylenecycloalkanols, and these noncyclopropyl products have been shown to arise by the isomerization of initially produced silyl cyclopropyl ethers with zinc iodide which is formed during the course of Simmons-Smith reaction.

原文English
頁(從 - 到)858-859
頁數2
期刊Journal of Organic Chemistry
39
發行號6
DOIs
出版狀態Published - 1 3月 1974

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