An efficient and selective method for preparing glycosyl sulfoxides by oxidizing glycosyl sulfides with OXONE* or t-BuOOH on SiO2

Ming Yi Chen; Laxmikant Narhari Patkar; Hui Ting Chen; Chun Cheng Lin

doi:10.1016/S0008-6215(03)00164-2

An efficient and selective method for preparing glycosyl sulfoxides by oxidizing glycosyl sulfides with OXONE* or t-BuOOH on SiO₂

Ming Yi Chen^*
, Laxmikant Narhari Patkar
, Hui Ting Chen
, Chun Cheng Lin

^*此作品的通信作者

藥學系

研究成果: Article › 同行評審

30 引文斯高帕斯（Scopus）

摘要

Silica gel adsorbed with OXONE or t-BuOOH was used as a mild oxidant to selectively oxidize glycosyl sulfides to corresponding sulfoxides in good yields and without sulfones formation. This method was also found compatible with various other functional groups in the glycosides.

原文	English
頁（從 - 到）	1327-1332
頁數	6
期刊	Carbohydrate Research
卷	338
發行號	12
DOIs	https://doi.org/10.1016/S0008-6215(03)00164-2
出版狀態	Published - 16 6月 2003

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10.1016/S0008-6215(03)00164-2

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title = "An efficient and selective method for preparing glycosyl sulfoxides by oxidizing glycosyl sulfides with OXONE* or t-BuOOH on SiO2",

abstract = "Silica gel adsorbed with OXONE or t-BuOOH was used as a mild oxidant to selectively oxidize glycosyl sulfides to corresponding sulfoxides in good yields and without sulfones formation. This method was also found compatible with various other functional groups in the glycosides.",

keywords = "Glycosyl sulfoxide, Oxidation, OXONE, Silica gel support, t-BuOOH",

author = "Chen, \{Ming Yi\} and Patkar, \{Laxmikant Narhari\} and Chen, \{Hui Ting\} and Lin, \{Chun Cheng\}",

note = "Funding Information: This research was supported by Academia Sinica and the National Science Council of Taiwan. (NSC 91-2113-M-001-013) ",

year = "2003",

month = jun,

day = "16",

doi = "10.1016/S0008-6215(03)00164-2",

language = "English",

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TY - JOUR

T1 - An efficient and selective method for preparing glycosyl sulfoxides by oxidizing glycosyl sulfides with OXONE* or t-BuOOH on SiO2

AU - Chen, Ming Yi

AU - Patkar, Laxmikant Narhari

AU - Chen, Hui Ting

AU - Lin, Chun Cheng

N1 - Funding Information: This research was supported by Academia Sinica and the National Science Council of Taiwan. (NSC 91-2113-M-001-013)

PY - 2003/6/16

Y1 - 2003/6/16

N2 - Silica gel adsorbed with OXONE or t-BuOOH was used as a mild oxidant to selectively oxidize glycosyl sulfides to corresponding sulfoxides in good yields and without sulfones formation. This method was also found compatible with various other functional groups in the glycosides.

AB - Silica gel adsorbed with OXONE or t-BuOOH was used as a mild oxidant to selectively oxidize glycosyl sulfides to corresponding sulfoxides in good yields and without sulfones formation. This method was also found compatible with various other functional groups in the glycosides.

KW - Glycosyl sulfoxide

KW - Oxidation

KW - OXONE

KW - Silica gel support

KW - t-BuOOH

UR - https://www.scopus.com/pages/publications/0038021204

U2 - 10.1016/S0008-6215(03)00164-2

DO - 10.1016/S0008-6215(03)00164-2

M3 - Article

C2 - 12791287

AN - SCOPUS:0038021204

SN - 0008-6215

VL - 338

SP - 1327

EP - 1332

JO - Carbohydrate Research

JF - Carbohydrate Research

IS - 12

ER -

An efficient and selective method for preparing glycosyl sulfoxides by oxidizing glycosyl sulfides with OXONE* or t-BuOOH on SiO2

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An efficient and selective method for preparing glycosyl sulfoxides by oxidizing glycosyl sulfides with OXONE* or t-BuOOH on SiO₂