A Palladium/Light System Combined with Hanztsch Ester: Radical Vinylation of Alkyl Iodides with Vinyl Bromides

Shuhei Sumino; Ilhyong Ryu

doi:10.1002/ajoc.201600547

A Palladium/Light System Combined with Hanztsch Ester: Radical Vinylation of Alkyl Iodides with Vinyl Bromides

Shuhei Sumino, Ilhyong Ryu^*

^*此作品的通信作者

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14 引文斯高帕斯（Scopus）

摘要

Radical vinylation of alkyl iodides with vinyl bromides proceeds smoothly with a combined Pd/light/Hanztsch ester system. In this reaction system, the Hanztsch ester acts as an effective reducing reagent of Pd^II to Pd⁰ that generates key alkyl radicals via single electron transfer (SET) with alkyl iodides upon photo-excitation.

原文	English
頁（從 - 到）	410-413
頁數	4
期刊	Asian Journal of Organic Chemistry
卷	6
發行號	4
DOIs	https://doi.org/10.1002/ajoc.201600547
出版狀態	Published - 4月 2017

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10.1002/ajoc.201600547

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title = "A Palladium/Light System Combined with Hanztsch Ester: Radical Vinylation of Alkyl Iodides with Vinyl Bromides",

abstract = "Radical vinylation of alkyl iodides with vinyl bromides proceeds smoothly with a combined Pd/light/Hanztsch ester system. In this reaction system, the Hanztsch ester acts as an effective reducing reagent of PdII to Pd0 that generates key alkyl radicals via single electron transfer (SET) with alkyl iodides upon photo-excitation.",

keywords = "Hanztsch ester, palladium, photocatalysis, radical reactions, redox chemistry",

author = "Shuhei Sumino and Ilhyong Ryu",

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AU - Ryu, Ilhyong

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N2 - Radical vinylation of alkyl iodides with vinyl bromides proceeds smoothly with a combined Pd/light/Hanztsch ester system. In this reaction system, the Hanztsch ester acts as an effective reducing reagent of PdII to Pd0 that generates key alkyl radicals via single electron transfer (SET) with alkyl iodides upon photo-excitation.

AB - Radical vinylation of alkyl iodides with vinyl bromides proceeds smoothly with a combined Pd/light/Hanztsch ester system. In this reaction system, the Hanztsch ester acts as an effective reducing reagent of PdII to Pd0 that generates key alkyl radicals via single electron transfer (SET) with alkyl iodides upon photo-excitation.

KW - Hanztsch ester

KW - palladium

KW - photocatalysis

KW - radical reactions

KW - redox chemistry

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DO - 10.1002/ajoc.201600547

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A Palladium/Light System Combined with Hanztsch Ester: Radical Vinylation of Alkyl Iodides with Vinyl Bromides

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