A Highly Conductive n-Type Coordination Complex with Thieno[3,2- b]thiophene Units: Facile Synthesis, Orientation, and Thermoelectric Properties

Kazuki Ueda; Riku Fukuzaki; Takumu Ito; Nana Toyama; Masahiro Muraoka; Toshiki Terao; Kei Manabe; Tomoyasu Hirai; Ching Ju Wu; Shih Ching Chuang; Shintaro Kawano; Michihisa Murata

doi:10.1021/jacs.2c07888

A Highly Conductive n-Type Coordination Complex with Thieno[3,2- b]thiophene Units: Facile Synthesis, Orientation, and Thermoelectric Properties

Kazuki Ueda, Riku Fukuzaki, Takumu Ito, Nana Toyama, Masahiro Muraoka, Toshiki Terao, Kei Manabe, Tomoyasu Hirai, Ching Ju Wu, Shih Ching Chuang, Shintaro Kawano, Michihisa Murata^*

^*此作品的通信作者

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研究成果: Article › 同行評審

6 引文斯高帕斯（Scopus）

摘要

An organometallic nickel complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and polyvinylidene difluoride, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm^-1). Moreover, the thermoelectric power factor of the n-type composite film was proven to be air stable. A grazing-incidence wide-angle X-ray diffraction analysis indicated a significant impact of introducing the thieno[3,2-b]thiophene core into the backbone of the nickel complex on the orientation within the composite films.

原文	English
頁（從 - 到）	18744-18749
頁數	6
期刊	Journal of the American Chemical Society
卷	144
發行號	41
DOIs	https://doi.org/10.1021/jacs.2c07888
出版狀態	Published - 19 10月 2022

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Ueda, K., Fukuzaki, R., Ito, T., Toyama, N., Muraoka, M., Terao, T., Manabe, K., Hirai, T., Wu, C. J., Chuang, S. C., Kawano, S., & Murata, M. (2022). A Highly Conductive n-Type Coordination Complex with Thieno[3,2- b]thiophene Units: Facile Synthesis, Orientation, and Thermoelectric Properties. Journal of the American Chemical Society, 144(41), 18744-18749. https://doi.org/10.1021/jacs.2c07888

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title = "A Highly Conductive n-Type Coordination Complex with Thieno[3,2- b]thiophene Units: Facile Synthesis, Orientation, and Thermoelectric Properties",

abstract = "An organometallic nickel complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and polyvinylidene difluoride, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm-1). Moreover, the thermoelectric power factor of the n-type composite film was proven to be air stable. A grazing-incidence wide-angle X-ray diffraction analysis indicated a significant impact of introducing the thieno[3,2-b]thiophene core into the backbone of the nickel complex on the orientation within the composite films.",

author = "Kazuki Ueda and Riku Fukuzaki and Takumu Ito and Nana Toyama and Masahiro Muraoka and Toshiki Terao and Kei Manabe and Tomoyasu Hirai and Wu, {Ching Ju} and Chuang, {Shih Ching} and Shintaro Kawano and Michihisa Murata",

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doi = "10.1021/jacs.2c07888",

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Ueda, K, Fukuzaki, R, Ito, T, Toyama, N, Muraoka, M, Terao, T, Manabe, K, Hirai, T, Wu, CJ, Chuang, SC, Kawano, S & Murata, M 2022, 'A Highly Conductive n-Type Coordination Complex with Thieno[3,2- b]thiophene Units: Facile Synthesis, Orientation, and Thermoelectric Properties', Journal of the American Chemical Society, 卷 144, 編號 41, 頁 18744-18749. https://doi.org/10.1021/jacs.2c07888

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T1 - A Highly Conductive n-Type Coordination Complex with Thieno[3,2- b]thiophene Units

T2 - Facile Synthesis, Orientation, and Thermoelectric Properties

AU - Ueda, Kazuki

AU - Fukuzaki, Riku

AU - Ito, Takumu

AU - Toyama, Nana

AU - Muraoka, Masahiro

AU - Terao, Toshiki

AU - Manabe, Kei

AU - Hirai, Tomoyasu

AU - Wu, Ching Ju

AU - Chuang, Shih Ching

AU - Kawano, Shintaro

AU - Murata, Michihisa

PY - 2022/10/19

Y1 - 2022/10/19

N2 - An organometallic nickel complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and polyvinylidene difluoride, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm-1). Moreover, the thermoelectric power factor of the n-type composite film was proven to be air stable. A grazing-incidence wide-angle X-ray diffraction analysis indicated a significant impact of introducing the thieno[3,2-b]thiophene core into the backbone of the nickel complex on the orientation within the composite films.

AB - An organometallic nickel complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and polyvinylidene difluoride, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm-1). Moreover, the thermoelectric power factor of the n-type composite film was proven to be air stable. A grazing-incidence wide-angle X-ray diffraction analysis indicated a significant impact of introducing the thieno[3,2-b]thiophene core into the backbone of the nickel complex on the orientation within the composite films.

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SN - 0002-7863

VL - 144

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EP - 18749

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 41

ER -

A Highly Conductive n-Type Coordination Complex with Thieno[3,2- b]thiophene Units: Facile Synthesis, Orientation, and Thermoelectric Properties

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