A Highly Conductive n-Type Coordination Complex with Thieno[3,2- b]thiophene Units: Facile Synthesis, Orientation, and Thermoelectric Properties

Kazuki Ueda, Riku Fukuzaki, Takumu Ito, Nana Toyama, Masahiro Muraoka, Toshiki Terao, Kei Manabe, Tomoyasu Hirai, Ching Ju Wu, Shih Ching Chuang, Shintaro Kawano, Michihisa Murata*

*此作品的通信作者

研究成果: Article同行評審

3 引文 斯高帕斯(Scopus)

摘要

An organometallic nickel complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and polyvinylidene difluoride, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm-1). Moreover, the thermoelectric power factor of the n-type composite film was proven to be air stable. A grazing-incidence wide-angle X-ray diffraction analysis indicated a significant impact of introducing the thieno[3,2-b]thiophene core into the backbone of the nickel complex on the orientation within the composite films.

原文English
頁(從 - 到)18744-18749
頁數6
期刊Journal of the American Chemical Society
144
發行號41
DOIs
出版狀態Published - 19 10月 2022

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