A general synthesis for ditungsten tetracarboxylates. Preparation of WW quadruple bonds by reductive-elimination (alkyl group disproportionation) from 1,2-diethyl compounds with WW triple bonds

M. H. Chisholm*, Hsin-Tien Chiu, J. C. Huffman

*此作品的通信作者

研究成果: Article同行評審

42 引文 斯高帕斯(Scopus)

摘要

A general high yield synthesis for W2(O2CR)4 compounds is proposed based on eqn (1), wherein a WW triple bond is converted to a quadruple bond, and this has been established for RMe, Et and t-Bu. W2Et2(NMe2)4 + 4RCOOCOR → W2(O2CR)4 + 4RCONMe2 + C2H4 + C2H6 (1).

原文English
頁(從 - 到)759-760
頁數2
期刊Polyhedron
3
發行號6
DOIs
出版狀態Published - 1 1月 1984

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