A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation

Jhe Cyuan Hu; Ai Fen Wendy Feng; Bo Yao Chang; Chun Hung Lin; Kwok-Kong Mong

doi:10.1039/c7ob00839b

A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation

Jhe Cyuan Hu, Ai Fen Wendy Feng, Bo Yao Chang, Chun Hung Lin, Kwok-Kong Mong^*

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摘要

A flexible 1,2-cis α-selective glycosylation strategy for a wide range of glycosyl donors and acceptors has been developed, which is based on an in situ adduct transformation protocol. Based on this strategy, both NFM-derived and iodide covalent adducts can be accessed for glycosylation. Using low temperature NMR spectroscopy, the aforementioned glycosyl adducts were detected.

原文	English
頁（從 - 到）	5345-5356
頁數	12
期刊	Organic and Biomolecular Chemistry
卷	15
發行號	25
DOIs	https://doi.org/10.1039/c7ob00839b
出版狀態	Published - 2017

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10.1039/c7ob00839b

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abstract = "A flexible 1,2-cis α-selective glycosylation strategy for a wide range of glycosyl donors and acceptors has been developed, which is based on an in situ adduct transformation protocol. Based on this strategy, both NFM-derived and iodide covalent adducts can be accessed for glycosylation. Using low temperature NMR spectroscopy, the aforementioned glycosyl adducts were detected.",

author = "Hu, {Jhe Cyuan} and Feng, {Ai Fen Wendy} and Chang, {Bo Yao} and Lin, {Chun Hung} and Kwok-Kong Mong",

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AU - Lin, Chun Hung

AU - Mong, Kwok-Kong

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AB - A flexible 1,2-cis α-selective glycosylation strategy for a wide range of glycosyl donors and acceptors has been developed, which is based on an in situ adduct transformation protocol. Based on this strategy, both NFM-derived and iodide covalent adducts can be accessed for glycosylation. Using low temperature NMR spectroscopy, the aforementioned glycosyl adducts were detected.

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A flexible 1,2-cis α-glycosylation strategy based on in situ adduct transformation

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