A Concise Route to Keto-Bridged Polyphenols by Photo-Fries Rearrangement in Flow

Xin Jie Lin, Chien-Lung Wang, Chi How Peng*, Hsueh Ju Liu*, Yen Ku Wu*

*此作品的通信作者

研究成果: Article同行評審

摘要

Described is a new synthetic route to bis(2-hydroxy-3,5-di-t-butylphenyl)methanone and its derivatives. The combined esterification/photo-Fries rearrangement approach enables a modular preparation of keto-bridged polyphenols. This protecting group-free process is highly atom- and step-economic, and a scalable production was easily achieved in the continuous-flow mode.

原文English
文章編號e202400269
期刊Chemistry - An Asian Journal
19
發行號13
DOIs
出版狀態Published - 2 7月 2024

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