@article{da351c68b652400389106a5294c9b014,
title = "A Bis-Cyclopentadienyl Ligand-Supported Di-Iron Trihydride Motif as a Synthon for Access to Heterobimetallic Trinuclear Complexes",
abstract = "Herein, we report the synthesis of a flexible bis-cyclopentadienyl ligand L (the doubly deprotonated form of H2L (1,3-bis(2,4-di-tert-butylcyclopentadienyldimethylsilyl)benzene)), demonstrating its ability to stabilize a series of di-iron hydrido complexes. Notably, this ligand facilitates the isolation of an unprecedented anionic cyclopentadienyl ligand-supported di-iron trihydride complex, LFe2(μ-H)3Li(THF) (2), functioning as a synthon for the [Fe2(μ-H)3]− core and providing access to heterobimetallic complexes 4-6 with coinage metals.",
author = "Tseng, {Chung Ching} and Ding, {Yi Wun} and Chen, {Zhong Yue} and Lan, {Hao Yuan} and Li, {Han Jung} and Cheng, {You Song} and Kuo, {Ting Shen} and Chen, {Pei Lin} and Wu, {Wen Chun} and Shi, {Fong Ku} and Tzuhsiung Yang and Liu, {Hsueh Ju}",
note = "Publisher Copyright: {\textcopyright} 2024 The Authors. Published by American Chemical Society.",
year = "2024",
month = jun,
day = "17",
doi = "10.1021/acs.inorgchem.4c01420",
language = "English",
volume = "63",
pages = "11361--11368",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "24",
}