1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion

Hsuch-Ju Liu; Julie Guihaumé; Thomas Davin; Christophe Raynaud; Odile Eisenstein; T. Don Tilley

doi:10.1021/ja507799e

1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion

Hsuch-Ju Liu, Julie Guihaumé, Thomas Davin, Christophe Raynaud, Odile Eisenstein^*, T. Don Tilley

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摘要

An intramolecular 1,2(α)-H migration in a saturated ruthenium stannylene complex, to form a ruthenostannylene complex, involves a reversal of the role for a coordinated stannylene ligand, from that of an electron donor to an acceptor in the transition state. This change in the bonding properties for a stannylene group, with a simple molecular motion, lifts the usual requirement for generation of an unsaturated metal center in migration chemistry.

原文	English
頁（從 - 到）	13991-13994
頁數	4
期刊	Journal of the American Chemical Society
卷	136
發行號	40
DOIs	https://doi.org/10.1021/ja507799e
出版狀態	Published - 8 10月 2014

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10.1021/ja507799e

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AU - Raynaud, Christophe

AU - Eisenstein, Odile

AU - Tilley, T. Don

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1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion

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