Transannular interactions in hexacyclo[6.6.0.0. 2,60. 3,130. 4,110. 5,9]tetradeca-10,14-dione

Tahsin J. Chow; Tung-Kung Wu

doi:10.1016/S0040-4039(00)72736-5

Transannular interactions in hexacyclo[6.6.0.0. ^2,60. ^3,130. ^4,110. ^5,9]tetradeca-10,14-dione

Tahsin J. Chow^*, Tung-Kung Wu

^*Corresponding author for this work

Department of Biological Science and Technology

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Transannular interaction between the two carbonyl groups of the titled compound is evidenced by C-13 NMR, X-ray and chemical reactions. Photolysis in isopropanol or tetrahydrofuran induces a pinacol-type reductive coupling between the two carbonyl groups.

Original language	English
Pages (from-to)	1279-1280
Number of pages	2
Journal	Tetrahedron Letters
Volume	30
Issue number	10
DOIs	https://doi.org/10.1016/S0040-4039(00)72736-5
State	Published - 1 Jan 1989

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title = "Transannular interactions in hexacyclo[6.6.0.0. 2,60. 3,130. 4,110. 5,9]tetradeca-10,14-dione",

abstract = "Transannular interaction between the two carbonyl groups of the titled compound is evidenced by C-13 NMR, X-ray and chemical reactions. Photolysis in isopropanol or tetrahydrofuran induces a pinacol-type reductive coupling between the two carbonyl groups.",

author = "Chow, {Tahsin J.} and Tung-Kung Wu",

year = "1989",

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AU - Chow, Tahsin J.

AU - Wu, Tung-Kung

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N2 - Transannular interaction between the two carbonyl groups of the titled compound is evidenced by C-13 NMR, X-ray and chemical reactions. Photolysis in isopropanol or tetrahydrofuran induces a pinacol-type reductive coupling between the two carbonyl groups.

AB - Transannular interaction between the two carbonyl groups of the titled compound is evidenced by C-13 NMR, X-ray and chemical reactions. Photolysis in isopropanol or tetrahydrofuran induces a pinacol-type reductive coupling between the two carbonyl groups.

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DO - 10.1016/S0040-4039(00)72736-5

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JO - Tetrahedron Letters

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IS - 10

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Transannular interactions in hexacyclo[6.6.0.0. ^2,60. ^3,130. ^4,110. ^5,9]tetradeca-10,14-dione

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